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Showing 1 to 2 of 2 for “"Sodium Aminodiboranates"”.
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Synthetic studies of sodium aminodiboranate salts with electronwithdrawing substituents
… 1, we describe the synthesis of three new sodium aminodiboranate salts, Na(BH3)2NRR′, with trimethylsilyl groups on nitrogen. These compounds – sodium N,N-bis-(trimethylsilyl)¬aminodiboranate, sodium N-trimethylsilylamino¬diboranate, and sodium N-methyl-N-trimethylsilylaminodiboranate – …
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Volatile metal borohydride complexes: synthesis and characterization of new chemical vapor deposition precursors
The complex sodium methylborohydride, Na(H3BCH3), can be prepared in high yield (83%) by the addition of trimethylboroxine, (H3C)3B3O3, to sodium aluminum hydride, NaAlH4. The subsequent reaction of two equivalents of sodium methylborohydride with the alkaline earth bromides; MgBr2, CaBr2, SrBr2, …