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Showing 1 to 3 of 3 for “"Scorpionates."”.
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An investigation of cyanopyrazole ligands and cyanopyrazole scorpionate ligands in the creation of novel transition metal complexes
… boron to create larger tridentate ligands called scorpionates. Their uses are numerous. Another reason pyrazole ligands are popular is their ability to be modified. Substitutions at the 3, 4 and 5 positions of the pyrazole ring allow for numerous combinations of both steric and electronic effects …
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Quantum Perspectives on Physical and Inorganic Chemistry
… catalytic cycle utilizing transition metal scorpionates to activate arene C-H bonds, and a presentation of the benchmarking of a new composite model chemistry (the correlation consistent composite approach, ccCA) for the prediction of classical barrier heights. Modeling the pyrazolate …
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Supporting Well-Defined Platinum Group Metals in Metal-Organic Frameworks for Heterogeneous Catalysis
… methodologies for generating well-defined PGM scorpionates on a MOF composed of Tpm-based linkers. Detailed structural studies of Pd(II) installed in the C₃ᵥ scorpionate sites reveals an unusually Pd(II)-Napical interaction between the bidentate Pd complex and the third uncoordinated pyrazole …