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Showing 1 to 2 of 2 for “"Scission (Chemistry)"”.
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Thermochemical Interconnectivities of Active Sites on Metal Oxides and their Catalytic Consequences in C−O Formation and C−H Scission Chemistry
… opposite directions at redox and Brønsted acid chemistry, results in negative correlations between HAE and DPE, whereas the shared electron transfer step, occurred in the same direction at redox and Lewis acid chemistry, results in positive correlations between HAE and −EA. These thermochemical …
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Substitution chemistry of the cobalt complexes RCCo3(CO)9 (R = H, CHO) with the diphosphine ligand: 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd). Syntheses, X-ray structures and reactivity.
The reaction between the tetrahedrane cluster RCCo3(CO)9{R = CHO (1), H (3)} and the redox-active diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3- dione (bpcd) leads to the replacement of two CO groups and formation of RCCo3(CO)7(bpcd) {R = CHO (2), H (4)}. Clusters 2 and 4 are …