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Showing 1 to 2 of 2 for “"Schwefelorganische Verbindungen"”.
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Palladium-katalysierte kinetische Racematspaltung allylischer Carbonate mit S-Nukleophilen und enantioselektive Umlagerung allylischer O-Sulfinate : asymmetrische Synthese von allylischern Sulfiden und Sulfonen
The palladium(0) catalyzed reactions of symmetrically disubstituted racemic allylic carbonates, being either cyclic or acyclic, with 2-pyrimidinethiol in the presence of N,N'-(1R,2R)-1,2-cyclohexanediyl-bis[2-(diphenylphosphino)-benzamide] BPA as ligand proceed with excellent levels of …
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Chirale Sulfonimidamide und Sulfoximine : Synthese, Strukturuntersuchungen und Anwendungen
This thesis describes the synthesis and structure determination of chiral sulfur-containing compounds, their use in asymmetric catalysis and the determination of the basicity of a bissulfoximine. In the first part the preparation of enantio- and diastereomerically pure sulfonimidamides bearing …