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Showing 1 to 2 of 2 for “"Ring-closing olefin metathesis"”.

  1. Synthesis of Taxol™ Analogs as Conformational Probes

    … Difficulties were encountered with the key ring-closing metathesis strategy, suggesting that a more flexible and efficient macrocyclization method will be needed to synthesize additional macrocyclic analogs.

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  2. Towards the Total Synthesis of Antascomicin B. Efforts to Construct the C1-C21 Fragment

    <p>Antascomicin B is a macrolide isolated from a strain of <em>Micromonospora</em>. It possesses structural similarities to FK506 and rapamycin and exhibits potent binding ability to FKBP12. Recent reports suggest that small molecule ligands of FKBP12 possess potent neuroprotective and …

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