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Showing 1 to 3 of 3 for “"Rhodium(I)-Catalyzed"”.
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Stereoselective Intramolecular Rhodium(I)-Catalyzed [(3+2+2)] Cycloaddition Reactions of Alkylidenecyclopropanes (ACPs) for the Concise Synthesis of Bridged Tricyclic Products
Transition metal-catalyzed higher-order [m+n+o] cycloadditions are an important class of reactions for constructing elaborate carbocycles and heterocycles in a highly convergent manner. In particular, cycloadditions with alkylidenecyclopropanes (ACPs) as three-carbon synthons offer a versatile …
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Synthesis and application of chiral dienes and chiral imidates as ligands for transition metal catalysis
… The synthesized diene ligands were tested in the rhodium(I)-catalyzed 1,4-addition of phenylboronic acids to cyclic enones (up to 96% ee) and α-acetamido acrylic ester and in the rhodium(I)-catalyzed 1,2-addition of phenylboronic acids to benzaldehydes (up to 48% ee). We introduced chiral imidates …
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Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes and Palladium-Catalyzed Carbon-Halogen Bond Forming Reactions
… the Lautens group involves the transition metal catalyzed asymmetric ring opening (ARO) of strained alkenes, which provides access to enantioenriched carbocyclic frameworks. Although a variety of coupling partners have been applied in this transformation, the use of soft carbon nucleophiles …