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Showing 1 to 7 of 7 for “"Reversible deactivation radical polymerization"”.
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Stereochemical Effect of RAFT Agents on Kinetics of Reversible Deactivation Radical Polymerization
… at chain ends to generate propagating radicals, which initiate subsequent chain extensions. Since the effect of remote substituents on kinetics decreases rapidly with their distance from the reaction site (chain ends), propagating radicals could be assumed to be only determined by the …
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Controlled Radical Polymerization: Towards Industrially Relevant Conditions
Reversible deactivation radical polymerization (RDRP), also known as controlled radical polymerization (CRP), has been a significant area of polymer research for more than 20 years, allowing the facile synthesis of complex macromolecules previously unattainable by conventional free radical …
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Visible Light-Mediated Polymerization for Protein-Polymer Conjugation: A Biocompatible Tool for Therapeutic Applications
… challenges. The development of controlled/living radical polymerization (CLRP) techniques (or also known as reversible-deactivation radical polymerization, RDRP) has been emerging since 1990’s to address these issues and refine the process. Notably, the recent advancements in photochemistry, such …
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Multiblock Copolymer Synthesis in Aqueous Heterogeneous Systems
The development of Reversible Deactivation Radical Polymerization (RDRP) techniques have revolutionized the field of polymer chemistry. These techniques provide the ease and flexibility of conventional radical polymerization, yet hold much of the control and livingness of anionic polymerization. …
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Synthesis and Characterization of Complex Polymer Topologies using Ring-Opening Metathesis Polymerization
… of monomer to polymer conversion in the reversible-deactivation radical polymerization (RDRP) step. Moreover, performing ring-opening metathesis polymerization (ROMP) initiated by Grubbs 3rd generation catalyst (G3) on a norbornene functionalized macromolecules allows for creating …
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Overcoming Challenges in Reversible Addition–Fragmentation Chain Transfer Polymerization using Photoinduced Electron/Energy Transfer Catalysis
The development of polymerization methodologies is discussed, with an emphasis on addressing two limitations in reversible addition–fragmentation chain transfer (RAFT) polymerization. Both methods employ photoinduced electron/energy transfer (PET) catalysis to generate radicals within the …