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Showing 1 to 3 of 3 for “"Reformatsky Reaction"”.
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Intramolecular [4+1] pyrroline annulation as a general method for the synthesis of pyrrolizidine alkaloids
… its regioisomer 2 by utilizing the vinylogous Reformatsky reaction, and the intramolecular additions of the azide moiety across the activated dienes with subsequent pyrolyses to provide the pyrrolizidines of type 3. This study broadened the scope of the vinylogous Reformatsky reaction to …
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The tandem chain extension -aldol reaction of beta-keto esters
<p>The Tandem Chain Extension-Aldol (TCEA) Reaction of beta-keto esters with aliphatic and aromatic aldehydes yields gamma-keto-beta'-hydroxy esters with significant syn-selectivity. A control Reformatsky reaction with a methyl 2-iodo-5,5-dimethyl-4-oxo-hexanoate 53 and methyl …