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Showing 1 to 20 of 48 for “"REDUCTION POTENTIALS"”.

  1. The Reduction Potentials of Some Inorganic Coordination Compounds

    Quagliano, James VincentUniversity of Illinois at Urbana-Champaign1946

    uiuc Repository record

  2. The Formal Oxidation-Reduction Potentials of Ferric-ferrous in Phosphoric Acid

    McFall, Inez ElizabethCreighton University1954

    The formal redox potentials of the ferric-ferrous system have been determined in the media of perchloric (15), nitric (12), hydrochloric (13), sulfuric (15), and phosphoric (l) acids. The acids are named in the order of increasing extent to which the oxidation potential of the ferric-ferrous system …

    creighton Repository record

  3. Physical consequences of natural and synthetic post-translational modifications

    Kilgore, Henry R.(Henry Ralph)Massachusetts Institute of Technology2020

    … and other enzymes that bear highly variable reduction potentials.

    mit Repository record

  4. Ribonucleotide reduction and redox regulation in Archaea : surprising twists on a common theme

    Hernandez, Hector HugoMassachusetts Institute of Technology2008

    To study the nucleotide reduction system in Archaea, we have expressed the Archaeoglobus fulgidus gene encoding the adenosylcobalamin (AdoCbl) dependent ribonucleotide reductase (afuRNR) protein. Initial characterization of the recombinant afuRNR indicates that it reduces CDP to dCDP in an AdoCbl …

    mit Repository record

  5. ΦΩΤΟΧΗΜΙΚΗ ΚΑΙ ΗΛΕΚΤΡΟΧΗΜΙΚΗ ΜΕΛΕΤΗ ΤΗΣ ΜΕΤΑΦΟΡΑΣ ΚΑΙ ΑΠΟΘΗΚΕΥΣΗΣ ΕΝΕΡΓΕΙΑΣ ΜΕ ΕΝΩΣΕΙΣ ΣΥΝΑΡΜΟΓΗΣ ΤΟΥ ΣΙΔΗΡΟΥ (ΙΙΙ)

    Μιχαήλ, ΧρυσόστομοςΑριστοτέλειο Πανεπιστήμιο Θεσσαλονίκης (ΑΠΘ)1987

    … THAT A LINEAR RELATIONSHIP EXISTS BETWEEN THE REDUCTION POTENTIALS AND THE Σ6Χ HAMMETT PARAMETERS OF THE SUBSTITUENTS OF THE CHELATE RING. THE FLASH PHOTOLYSIS SHOWED THAT THE DECAY OF THE TRIPLET STATE OF ORGANIC COMPOUNDS BY THE COMPOUNDS FE (ACAL-CL)3 AND FE (BDO)3 WAS DUE TO ENERGY TRANSFER …

    greece Repository record

  6. Enzymatic activation of cytochrome P-450(cam)

    Martinis, Susan AnneUniversity of Illinois at Urbana-Champaign2011

    … of the reconstituted proteins. In addition reduction potentials were measured and the ability of the chlorin-substituted proteins to carry out native and redox activity was investigated.

    uiuc Repository record

  7. Synthesis of photochemically active complexes for DNA recognition and binding

    Luo, Jingwei2009

    … and [Ru(P)3](PF6)2 do not seem to have reduction potentials in the excited states that are appropriate for nucleic base photo-oxidation.

    queens Repository record

  8. Proton-coupled electron transfer reactions in bio-inspired catalysis

    Huynh, Mioy TUniversity of Illinois at Urbana-Champaign2017

    … for hydrogen production, with rates and overpotentials comparable to leading, synthetic Pt catalysts while utilizing earth abundant metal centers in their active sites. Density functional theory calculations, in conjunction with complementary experiments, were conducted to understand the …

    uiuc Repository record

  9. ΦΑΣΜΑΤΟΣΚΟΠΙΚΗ ΚΑΙ ΗΛΕΚΤΡΟΧΗΜΙΚΗ ΜΕΛΕΤΗ ΕΝΩΣΕΩΝ ΣΥΝΑΡΜΟΓΗΣ ΤΟΥ ΚΟΒΑΛΤΙΟΥ (ΙΙΙ) ΚΑΙ ΧΑΛΚΟΥ (ΙΙ) ΜΕ Β-ΔΙΟΝΕΣ

    Cambanis, Stavros, Καμπάνης, ΣταύροςAristotle University Of Thessaloniki (AUTH)1989

    … FREQUENCIES AS WELL AS THE POLAROGRAPHIC REDUCTION POTENTIALS ARE LINEARELY DEPENDENT ON HAMMETT Σ FUNCTIONS. IN THE CASE OF CO(III) CHELATES SIMILARLY DEPENDENT ARE THE RACAH PARAMETER B AND THE ENERGY OF THE FRONTIER MOLECULAR ORBITALS. FURTHERMORE IT WAS ESTABLISHED THAT THE INDUCTIVE …

    greece Repository record

  10. STRUCTURE REFINEMENT OF CYTOCHROME C555 (CHLOROBIUM, THIOSULFATOPHILUM).

    JORDAN, STEVEN RALPH.The University of Arizona.1983

    … evolutionary implications. Second, the oxidation-reduction potential of cytochrome c₅₅₅ is significantly different from the oxidation-reduction potential of other cytochromes whose structures have been determined. Comparisons with the other structures would provide information concerning the …

    arizona-thes Repository record

  11. Influence of Iron Speciation on Redox Cycling and Reactivity With Persistent Organic Contaminants

    Kim, DongwookUniversity of Illinois at Urbana-Champaign2015

    … Observed reaction rate constants for contaminant reduction measured in batch reactions (kobs, s-1 ) increase with ligand concentration and pH when FeII concentration is fixed. Correlation analysis reveals that a single Fe II species typically dominates overall FeII reactivity with target compounds …

    uiuc Repository record

  12. Thermodynamic Studies of Metal Carboxylates

    Long, John ReidUniversity of Illinois at Urbana-Champaign2014

    … in (pi)-backbonding to the ligands. The reduction potentials of Rh(,2)(C(,4)H(,7)O(,2))(,4)('+), Rh(,2)(C(,4)H(,7)O(,2))(,4)B('+), and Rh(,2)(C(,4)H(,7)O(,2))(,4)B(,2)('+) are analyzed, and provide further support for the extensive (pi)-backbonding capabilities of this metal cluster.

    uiuc Repository record

  13. Rearrangements of Radical Anions Generated from Cyclopropyl Ketones

    Phillips, Janice PaigeVirginia Tech1998

    … using homogeneous catalysis techniques. Standard reduction potentials and reorganization energies of substrates were derived using Marcus theory. Conjugative interactions with the cyclopropyl group are discussed.

    vt Repository record

  14. Relative rates of reaction of pyrite and marcasite with ferric iron at low pH

    Wiersma, Cynthia LeighVirginia Polytechnic Institute and State University1982

    … + 16H⁺ was determined by calculating the rate of reduction of aqueous ferric ion from measured oxidation-reduction potentials. The reaction follows the rate law: -d m<sub>Fe³⁺</sub> / dt = k (A/M) m<sub>Fe³⁺</sub> where m<sub>Fe³⁺</sub> is the molal concentration of uncomplexed ferric iron, k is …

    vt Repository record

  15. Smart Building Energy Management System for Energy Efficiency and Demand Response

    Alrashidi, Massoud Owihan W.Virginia Tech2023

    … forecasting, optimized scheduling, and load reduction potentials. Firstly, machine learning applications are used to derive a novel data-driven short-term predictive strategy to forecast the future values of solar radiation and PV power output. It allows for precise forecasts of thermal …

    vt Repository record

  16. M28 Fixed wing transport aircraft cost reduction

    Xia, YuXin, M.B.A. Sloan School of ManagementMassachusetts Institute of Technology2011

    … need to be reduced significantly. Multiple cost-reduction concepts have been proposed by the manufacturing and procurement groups. An Optimization Team was also formed to lead the cost-reduction effort. However, a more systematic approach is required in order to achieve the ambitious reduction …

    mit Repository record

  17. Characterisation of OmcA From Shewanella oneidensis MR-1: Biophysical and Mineral Reduction Properties

    Baiden, NanakowUniversity of East Anglia2014

    … inal!electron!transfer!during!respiratory!mineral!reduction,!but!has!minimal! or! contrasting! properties! in! the! literature.! A! suite! of! biophysical! techniques! confirmed!the!bis?histidine!axial!ligation!of!all!OmcA’s!haem!content!in!the!crystal! structure! and! in! …

    east-anglia Repository record

  18. Molecular electrocatalysis of hydrogen evolution: catalytic design studied by density functional theory

    Solis, BrianUniversity of Illinois at Urbana-Champaign2014

    … molecular hydrogen evolving electrocatalysts. Reduction potentials and pKa’s were calculated for a variety of complexes with density functional theory in conjunction with appropriate experimental references in order to characterize the thermodynamics of the free energy of reaction for proton …

    uiuc Repository record

  19. The effect of alternative fuels and aftertreatment devices on measured mobile school bus emissions

    Toback, Andrew Todd2016

    … also tested.</p> <p>In order to evaluate the reductions, all tests were performed using a drive cycle developed by Rowan University. This drive cycle is a composite cycle developed from 11 actual school bus routes. The results reported herein were obtained by performing the drive cycle on a …

    rowan Repository record

  20. The Physical Chemistry Underlying the Assembly and Midpoint Potential Control in a Series of Designed Protein-Maquettes

    Solomon, Lee Andrew2013

    … oxygen transport (hemoglobins), oxygen reduction (oxidases), carbon-hydroxylation (oxygenases), and superoxide production (NADH oxidase). In natural oxidoreductases, determination of the course and rates of heme-protein association, what barriers are encountered, what affinity is …

    penn Repository record

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