Global ETD Search
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Showing 1 to 3 of 3 for “"Porous Organic Cages"”.
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Understanding reaction pathways leading to tetrahedral organic cages via alkyne metathesis
Porous organic cages (POCs) have garnered great interest due to their well-defined structural porosity and solution processability that provide advantageous properties for wide ranges of applications. Recently, the feasibility of constructing various POCs via multitopic dynamic covalent chemistry …
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The Synthesis and Application of 1,4-Dithiins, Thianthrenes, and Other Sulfur-Rich Scaffolds
… In Chapter 5, we discuss our approach towards porous organic cages. Rational design of a macrocycle as well as attempts for its production and isolation are disclosed. Though we were unable to produce our desired scaffold, we have synthesized useful intermediates that enable access to sulfurous …
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Predicting precursor size effects on organic cage formation with molecular dynamics
The recently developed porous organic molecular cage is a promising class of porous materials, which has already opened new ways for specific reaction environment development, molecular separation and storage, and catalysis. Creation of these small porous cage molecules is challenging because there …