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Showing 1 to 18 of 18 for “"Polyphosphoric acid"”.
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Polyphosphoric Acid as a Reagent in Organic Chemistry
Made available in DSpace on 2014-12-05T19:35:54Z (GMT). No. of bitstreams: 1 0009066.pdf: 4614760 bytes, checksum: f3cd93860f8823da438c9df100c13312 (MD5) Previous issue date: 1954
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Products From the Condensation of Acetophenone by Polyphosphoric Acid
Made available in DSpace on 2014-12-05T19:36:11Z (GMT). No. of bitstreams: 1 0013500.pdf: 2338837 bytes, checksum: 536159981c02d7697bd21ef200117c79 (MD5) Previous issue date: 1955
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The Hydrocarbons From The Polyphosphoric Acid Induced Condensation of Acetophenone
Made available in DSpace on 2014-12-05T19:36:38Z (GMT). No. of bitstreams: 1 0023318.pdf: 3336335 bytes, checksum: caf7d1a347de4995ec7c579a95e0d6bf (MD5) Previous issue date: 1957
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I. Substituted Bis-Arene-Chromium Compounds. Ii. Structures of Hydrocarbons From the Polyphosphoric Acid Induced Condensation of Acetophenone
Made available in DSpace on 2014-12-05T19:37:19Z (GMT). No. of bitstreams: 1 6001622.pdf: 3296636 bytes, checksum: 9552193003b080db3bc5488586701a5a (MD5) Previous issue date: 1960
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Novel Polyphenylquinoxaline and Polybenzimidazole Proton Exchange Membranes For High Temperature Fuel Cell Systems
… suitable for high temperature PEMFCs where polyphosphoric acid (PPA) is used as a condensation agent and as a casting solvent in a one-pot synthesis of polymer suitable for proton exchange membranes. This process, termed the "PPA Process," produces high molecular weight polymer with a …
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A study of the synthesis and reactions of new polynuclear aromatic acids and related compounds
… carbinols during the distillation step. The keto-acid, 2-(3-chloro-l-naphthylmethyl)- 2’-carboxybenzophenone was prepared by the inverseaddition of the Grignard reagent of 2-(3-chloro-l-naphthylmethyl)bromobenzene to phthalic anhydride. Cyclization of this keto-acid with an acetic and hydrobromic …
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Synthesis and Chacterization of Novel Polybenzimidazoles and High-Solids Meta-Polybenzimidazoles
… temperature PEM fuel cell systems, which uses polyphosphoric acid (PPA) as both the polycondensation agent and the casting solvent. This one-pot process, called the 'PPA Process', allows for the synthesis of high molecular weight polymer membranes with high acid-loading levels and good …
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Exploring the Black Space of Compressive and Shear Modulus
… the other three were modified with polymers and acids. Additionally, Polyphosphoric acid (PPA) is compared to the more traditional SBS polymer modification. PPA is currently prohibited in Arkansas because of a lack of information on its field performance. Three tests were performed: Uniaxial …
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Some chemistry of bromobenzopyrans
… of a phenol with an a,j3-unsaturated carboxylic acid. 2,4-Dimethylphenyl-3-methylbut-2-enoate was obtained as a by-product during the preparation of 2,2,6,8 tetramethylchroman-4-one from 2,4-dimethyiphenol and 3,3-dimethylacrylic acid in polyphosphoric acid. The ester in polyphosphoric acid …
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The synthesis of novel indazole alkaloids with potential medicinal properties.
… a novel approach in which four p-monoacylated acid hydrazides 7a-d were prepared for cyclisation into indazoles 8a-d. Reaction of phenylhydrazine with benzoyl chloride, 4-benzyloxy benzoyl chloride and 4-nitrobenzoyl chloride gave hydrazides 7a-c whilst reaction of and 2-ethylphenyl hydrazine …
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Approaches to the synthesis of diazabiphenylenes
… of the dioxime(s) of this diketone and polyphosphoric acid then used as a catalyst to give the expected cis,trans,cis-4,10-diazatricyclo[6,4,0,0 2,7]- dodecane-3,9-dione as the major product. The Schmidt reaction of the diketone gave the known cis,trans,cis- 3,9-diazatricyclo[6,4,0,0 …
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Synthesis of Mononuclear Transition Metal Complexes and their Applications as Catalysts for Ethylene Polymerization
… synthesized via condensation reactions using polyphosphoric acid which acts as solvent, oxidizing and dehydration agent. The condensation reactions proceeded readily to produce high yield products. Bis(benzimidazole)s can also be prepared by refluxing the reactant in 4 N hydrochloric acid for …
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A study of aromatic cyclodehydration, I. Ortho effects II. The catalytic effect of metal oxides
… out in a sealed tube in hydrobromic and acetic acids at 150°C rather than at 117.5°C which was the temperature used previously. This increase was necessary to get a reaction with all the ketones concerned. Even under these conditions the 2'-hydroxy-2- benzylbenzophenone cyclized very poorly. …
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Mechanical and surface free energy characterization of asphalt concrete for moisture damage detection
… butadiene styrene (SBS), SBS with LAS, and polyphosphoric acid (PPA) with HL. The effects of the additives and modifiers on the moisture susceptibility of the proposed AC mixtures were evaluated through several mixture- and component-level tests. The mixture-level tests are the modified …
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Synthesis and investigation of benzimidazole and carbazole ß-haematin inhibiting scaffolds with antimalarial activity
… synthesis, via a condensation reaction using polyphosphoric acid (PPA), 4-aminobenzoic acid and o-phenylenediamine to form the primary amine benzimidazole intermediate after which ani acylation reaction with the appropriate acid chloride furnished the desired compounds. β-haematin inhibition …