Global ETD Search
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Showing 1 to 2 of 2 for “"Piancatelli Rearrangement"”.
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Method Development Towards Catalytic Transformations of Reactive Intermediates
… a unique palladium-silver catalyzed aza-Piancatelli rearrangement of furcarbinol acetates was explored in chapter four. An in situ IR monitoring technique was used to extrapolate mechanistic insight from preliminary kinetic data. A cationic palladium species was proposed to act as the …
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Carbon monoxide-driven reductive organic transformations and precious metals recycling
… which undergo a newly-identified, reductive Piancatelli rearrangement to yield 2-enoneamines. A novel Pd/Rh dual‐metallic cooperative catalytic process has been developed to effect the reductive carbonylation of aryl halides in moderate to good yield. In this reaction, water is the hydride …