Global ETD Search
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Showing 1 to 3 of 3 for “"Phosphate tethers"”.
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Phosphate Tethers in Synthesis: The Total Synthesis of Dolabelide C.
The utilization of phosphate tethers in synthesis is the focus of the dissertation research described herein. Specifically, cross metathesis of various olefin partners with a phosphate tether has been demonstrated. These studies established the Type III olefin reactivity of the exocyclic olefin of …
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Multivalent activation in temporary phosphate tethers: A new tether for small molecule synthesis
The use of phosphate esters as temporary tethers, capable of multivalent activation is the broad focus of the dissertation research reported herein. Specifically, the utility of phosphate tethers has been demonstrated through the divalent activation of allylic C2-symmetric monocyclic phosphates. …
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Phosphate Tether-Mediated, One-Pot Metathesis Processes: Application in Small Molecule Synthesis
… is to utilize the empowering ability of phosphate tethers to mediate a series of reactions towards the synthesis of bioactive molecules by exploiting several salient features inherent to organophosphates, including (i) orthogonal stability under acid conditions, (ii) possessing leaving …