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Showing 1 to 2 of 2 for “"Peroxyester Synthesis"”.
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The synthesis of peroxyesters
… herein was to establish an alternative route to peroxyester formation, using milder conditions and following a more simplified laboratory procedure to those of methods presently known The positive results obtained were via carbocation intermediates, and disproved the claim by Magelli and Sheppard …
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Towards Water-Soluble Peroxyl Radial Clocks
Peroxyesters undergo homolytic O-O bond cleavage under thermal and photolytic conditions, forming an alkoxyl and acyloxyl radical, the latter of which rapidly decarboxylates to form a carbon centered radical. While peroxyesters are generally decomposed under anaerobic conditions to serve as sources …