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Showing 1 to 5 of 5 for “"Pd0"”.
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Development and application of bioorthogonal palladium- labile derivatives of cytotoxic pyrimidine analogues
… it describes the synthesis of palladium (Pd0) functionalized resins (the activating device) capable of activating cytotoxic pyrimidine analogue prodrugs masked with Pd0-labile protecting groups. Both the Pd0 functionalized resins and the BOOM-activated prodrugs are independently …
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Understanding the effects of promoters on the direct synthesis of hydrogen peroxide over supported palladium catalysts
… conditions, Pd can exist in heterogeneous (Pd0) as well as homogeneous (Pd2+) forms and both these forms of Pd can potentially contribute to catalysis. In chapter 2, we demonstrate, by a combination of kinetic measurement and in situ UV-Vis spectroscopy, that the heterogeneous Pd0 …
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Multidentate phosphino-alkene ligands and their late transition metal complexes
… non-coordinated alkenes is observed in both the Pd0 complex, 167, and the related cationic CuI complex, 193. An investigation into the CuI complexes’ activity in the cyclopropanation of styrene, as catalysts, showed that they are commensurate with other recently reported systems. In addition to …
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Sensitive Electrochemical Detection Platforms for Anthracene and Pyrene
… dass die Zusammensetzung der NPs von Pt2+ und Pd0 dominiert wird. Die XRD-Analyse ergab eine kristalline Natur mit einer flächenzentriert-kubischen Struktur. Die Pt-Pd-NPs bewirkten eine Erhöhung des Spitzenstroms um 94 % für Pyren, führten jedoch zu niedrigeren Spitzenströmen für Anthracen. …
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Coordination chemistry of unusual oxidation states of nickel and palladium relevant to homogeneous catalysis
… in photodriven elementary steps involving Pd0 and PdII-methyl complexes. This intermediate demonstrates the role of paramagnetic states in Pd catalysis.