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Showing 1 to 2 of 2 for “"Oxidative Heck Vinylation"”.
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Oxidative Heck Reactions with Terminal Olefins
… terminal olefin for the vinylic C—H arylation (Heck reaction). This manifold is unique because previous intermolecular Heck reaction conditions require an excess of resonance activated olefin coupling partner. Further exploration of directing groups to determine the underlying directing factors …
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Selective C—H oxidations for complex molecule synthesis and diversification
… versatility. A highly selective intermolecular oxidative Heck vinylation is also described that forms di- and polyenes from simple α-olefins. Notably the Heck reaction requires only one pre-activated coupling partner. While traditional intermolecular Heck reactions are generally limited to …