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Showing 1 to 1 of 1 for “"Oxa-azulenones"”.
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Novel synthetic methodology employing transition metal catalysed reactions of α-diazo-β-keto sulfonamides and α-cyano-α-diazoacetates; the impact of substituents on the reaction pathway
… lead to a number of different products including oxa-azulenones (up to 53% ee) arising from intramolecular aromatic addition, overcyclopropanation products (as single diastereomers) from the unanticipated cyclopropanation of oxa-azulenones and cyanohydrins from reaction with adventitious water. …