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Showing 1 to 6 of 6 for “"Organosulfur chemistry"”.

  1. Predicting organosulfur chemistry in fuel sources

    … mechanisms for other processes relevant in fuel chemistry, such as the geological formation of oil and gas from kerogen. This not only allows us to model experimental work investigating the effect sulfur compounds have on the oil-to-gas process, but we also explore how these effects differ at …

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  2. Novel synthetic methodology employing organosulfur chemistry in the synthesis of chalcone derivatives

    Highly functionalised a-thio-b-chloroenones are extremely useful synthetic intermediates. Their formation through a N-chlorosuccinimide (NCS) mediated chlorination cascade is a powerful synthetic methodology which transforms an unreactive sp3 b-carbon into a highly reactive sp2 …

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  3. Organometallic Chemistry in Fe–S Clusters

    The organometallic chemistry of Fe–S clusters has emerged as a new area in Fe–S enzyme biochemistry. In particular, alkylated [Fe₄S₄] clusters are now thought to be important intermediates in several classes of enzymes, including radical S-adenosyl-L-methionine (SAM) enzymes and enzymes involved in …

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  4. Laboratory studies of atmospheric photochemistry in indoor and outdoor environments

    … This work investigates the atmospheric photochemistry of indoor and outdoor environments, giving particular attention to the reactions that lead to SOA formation, notably those involving oxidant and peroxy radical (RO2) chemistry. First, this thesis examines the oxidation of dimethyl sulfide …

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  5. The powerful combination of novel organosulfur methodology and continuous flow technology

    … to deliver powerful transformations based on organosulfur chemistry. The main objective of this work was the synthesis of key building-blocks for biologically relevant compounds coupled with the use of Process Analytical Technologies (PAT), to gain critical mechanistic insight and …

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  6. Design and synthesis of novel sulfur-containing antiviral analogues

    … described later in the thesis. The medicinal chemistry of the nucleoside reverse transcriptase inhibitor (NRTI) class of anti-HIV compounds is described in Chapter Two. Our proposed synthetic target, an analogue of Adefovir Dipivoxil, is described alongside our rationale for studying this …

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