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Showing 1 to 8 of 8 for “"Organoiron"”.
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Synthesis, structures and studies of organoiron compounds
An A value of 3.7 kcal/mole was determined for the (η⁵-cyclopentadienyl) iron (II) dicarbonyl group by variable temperature ¹H NMR spectroscopic studies on cis-4-phenyl-1-(η⁵-cyclopentadienyl) iron (II) dicarbonyl cyclohexane. This is the first determination of the A value of a group with a …
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Synthetic, structural and molecular modelling studies of organoiron complexes of catalytic importance
The synthesis and characterization of a series of new alkyl dicarbonyl pentaznethylcyclopentadienyl iron compounds, [(η⁵-C₅(CH₃)₅)Fe(CO)₂R], is the starting point for an investigation of these compounds and their relevance as models for catalytic reactions. The compounds have been synthesized by …
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Triphenylmethylium-Based Multitopic Two-Photon Absorbers: Synthesis and Characterization
… absorption, Malachite Green, Violet Crystal, Organoiron, Organoruthenium, ferrocene, redox commutation
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Triphenylmethylium-Based Multitopic Two-Photon Absorbers: Synthesis and Characterization
… absorption, Malachite Green, Violet Crystal, Organoiron, Organoruthenium, ferrocene, redox commutation
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Organometallic Chemistry in Fe–S Clusters
… radical SAM enzymes, and connects the organoiron and organosulfur chemistry.
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The synthesis, structure and chemistry of some novel organometallic dendrimers
… the metals. The thermal behaviour of some of the organoiron dendrimers was also investigated by thermogravimetric analysis and differential scanning calorimetry. The latter traces generally showed one endothermic peak which could be assigned to melting. The chemical reactivity of a first …
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Development of base metal-catalyzed C—H functionalization reactions
… C—H cleavage and rebounds from the resulting organoiron intermediate to form the new C—C bond; both of these steps are tunable via catalyst modifications. These studies suggest that for iron carbenes, distinct from other late metal carbenes, C—H cleavage is partially rate-determining and must …
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Synthesis and chemistry of thione-iron carbonyl complexes
<p>The first examples of sulfur-donor ligand <i>ortho</i>-metallated complexes were obtained in good to excellent yields by reaction of various thiobenzophenones and a thiobenzoate with diiron enneacarbonyl in benzene at room temperature. The known trinuclear complex …