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Showing 1 to 2 of 2 for “"Olefin difunctionalization"”.
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HYPERVALENT IODINE-MEDIATED HETEROCYCLIC GROUP TRANSFER REACTIONS TO OXIDATIVE OLEFIN DIFUNCTIONALIZATION
… of 3-aminopiperidine salts via diamination of olefins (Chapter 3). Both methods are promoted by nitrogen-ligated hypervalent iodine reagents (N-HVIs). These novel class of reagents serve as “heterocyclic group transfer reagents,” incorporating diverse pyridinium salts under mild conditions and …
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Mechanistic Studies and Rational Catalyst Design of Nickel/Photoredox Dual-Catalyzed C–C Cross-Coupling Reactions
… the mechanism of a novel enantioselective olefin difunctionalization was computationally investigated, identifying the radical addition step as the enantioselectivity-determining step (Chapter 4). Expanded to a wider scope of catalytic systems and reagents, the catalytic cycles of an …