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Showing 1 to 2 of 2 for “"O-H insertion"”.
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Exploring the reactivity of alpha-triorganylsilyl alpha-diazo esters : C-H activation, insertion reactions, and rearrangements
… with an emphasis on: · Dirhodium(II)-catalyzed insertions of Alpha-triorganylsilyl Alpha-diazo esters into activated C-H bonds. · Dirhodium(II)-catalyzed reactions of -triorganylsilyl Alpha-diazo esters with various acyclic and cyclic carbonyl precursors. · The syntheses of …
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Oxidation of Disinfection Byproducts and Algae-related Odorants by UV/H₂O₂
… or interaction with water molecule causing O-H insertion/H-Br elimination. Trichloromethane and mono-, di-, and tri-chlorinated HAAs were not substantially removed under the same conditions used for the brominated compounds. The principal removal mechanism was by the reaction with hydroxyl …