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Showing 1 to 3 of 3 for “"Nitrosoarene"”.
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An NMR Spectroscopy and Density-Functional Theory Study of Organometallic Complexes and Heme Proteins With Carbonyl, Alkylisocyanide, Nitrosoarene and Olefin Ligands: Applications to Structure Determinations
In this thesis I describe how density functional theory methods can be combined with NMR spectroscopy to determine ligand binding geometries in organometallic complexes and heme proteins. Results of density functional studies on compounds with well characterized structures are presented to test the …
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Studies on a catalytic cadogan cyclization by PI̳I̳I̳/PV̳=O redox cycling
… o-nitrobenzaldimine to 2-phenylindazole. A nitrosoarene, presumed an intermediate in the overall cyclization, was found to undergo cyclization under reaction conditions. In addition, a new unique oxazaphosphetane was observed as an intermediate during the course of cyclization, which may …
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En-Reaktion von Nitrosoaren, Triazolindion und Singulettsauerstoff
Im Rahmen der vorliegenden Arbeit wurde der Mechanismus der En-Reaktion von Nitrosoaren (ArNO), Triazolindion (TAD) und Singulettsauerstoff (1O2) durch Bestimmung von kinetischen Isotopeneffekten, Regioselektivitäten und Diastereoselektivitäten mit ausgewählten, deuteriummarkierten Olefinsubstraten …