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Showing 1 to 1 of 1 for “"Negative catalysis"”.
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Lewis base catalyzed enantioselective sulfenoamination of alkenes
The concept of Lewis base activation of Lewis acid has been successfully applied to the enantioselective sulfenoamination of olefins. The unreactive, achiral Lewis acidic sulfenylating agent, N-arylthiophthalimide, is activated by the coordination of a chiral Lewis base, binaphthyl-derived …