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Showing 1 to 1 of 1 for “"NH Insertion"”.
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Synthesis and reactivity of alpha-trialkylsilyl alpha-amino acids
… protocol involving rhodium(II)-catalysed insertion reactions of alpha-trialkylsilyl alpha-diazo esters into N-H bonds of carbamates. As an extension to this procedure, it was accounted that a diastereoselective approach to N-protected alpha-trialkylsilyl alpha-amino acids precursors may …