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Showing 1 to 2 of 2 for “"NEPHELAUXETIC EFFECT"”.
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Determining Optical Basicity of Molten Chloride Salts for Solar Thermal Applications
… from ligands in the molten salt, via the nephelauxetic effect of an added probe ion. In this work the OB of several alkali and alkaline earth chloride salts was measured by doping them with d10s 2 probe ions, Pb2+ and Bi3+, and quantifying the probe ion's redshift relative to that observed …
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ΦΑΣΜΑΤΟΣΚΟΠΙΚΗ ΚΑΙ ΗΛΕΚΤΡΟΧΗΜΙΚΗ ΜΕΛΕΤΗ ΕΝΩΣΕΩΝ ΣΥΝΑΡΜΟΓΗΣ ΤΟΥ ΚΟΒΑΛΤΙΟΥ (ΙΙΙ) ΚΑΙ ΧΑΛΚΟΥ (ΙΙ) ΜΕ Β-ΔΙΟΝΕΣ
… IT WAS ESTABLISHED THAT THE INDUCTIVE EFFECTS MODIFY THE SPHERICAL PORTION OF THE LIGAND FIELD AND THAT THE NEPLELAUXETIC EFFECT MUST BE CONSIDERED AS THE RESULT OF BOTH KINDS OF COVALENT INTERACTIONS. THE FIRST CT BAND IS ASSIGNED TO A P*--T2GEXCITATION. THE EXPERIMENTALLY DETERMINED …