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Showing 1 to 7 of 7 for “"N-heterocycle"”.
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The Study of Au(III) Compounds and their Interaction with Zinc Finger Proteins
… expanded this system to Au(III)-(nucleobase/N-heterocycle) compounds. Novel Au(III)(dien)(N-heterocycle) compounds, including the first Au(III)N3(N-purine) examples, were synthesized. As previously reported for [AuCl(dien)]Cl2, these compounds exhibit pH dependency of the 1H NMR chemical shifts …
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HARNESSING NATURE’S MACHINERY: CHARACTERIZATION OF BACTERIAL BIOSYNTHETIC ENZYMES FOR CHALLENGES IN ORGANIC SYNTHESIS
… of our novel method for biocatalytic N-heterocycle formation. We also include a discussion of our attempts towards enzymatic cofactor generation and recycling to improve the activity of our cryptic sulfotransferases. In Chapter 4, we report novel activity of DszA, a C–S bond cleavage …
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Interactions of platinum compounds with heterocyclic bases.
… of the type cis-PtCl2L2, where L is a N-heterocycle, have been successfully prepared and characterized. The kinetics of the reaction between K2PtCl4 and the N-heterocyclic bases in aqueous solution have beeD studied. This was best achieved by pre-aquating the PtCl4(2-) and measuring the …
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Hydrothermal Liquefaction of Municipal Sludge: Feedstock Composition, Inorganic Interactions, and Co-Liquefaction as a Dewatering Alternative
… in the biochar, whereas Na2CO3 promoted N-heterocycle formation in the biocrude and provided no enhancement in phosphorus recovery. The third study demonstrated that direct blending of dilute WAS with dry pistachio shells reaches the 20 wt.% solids HTL target without mechanical dewatering. …
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Development of Deactivation-Resistant Catalysts for Pd-Catalyzed C–N Cross-Coupling Reactions
… (1) unhindered, (2) five-membered-ring N-heterocycle-containing, and (3) α-tertiary primary amines, each of which previously required a different catalyst to achieve optimal results. Chapter 3: Pd-Catalyzed Amination of Base-Sensitive Five-Membered Heteroaryl Halides with Aliphatic Amines …
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Platinum Complexes and Zinc Finger Proteins: From Target Recognition to Fixation
<p>Bioinorganic chemistry strives to understand the roles of metals in biological systems, whether in the form of naturally occurring or addition of non-essential metals to natural systems. Metal ions play vital roles in many cellular functions such as gene expression/regulation and DNA …
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ESIMS targeted synthesis of novel {Pt2S2} derivatives
… to contain a novel 6-membered Pt-S-Pt-S-C-N heterocycle. 38 was characterised using NMR spectroscopy (1H, 13C, 31P{1H}, and 195Pt{1H}). 39 was characterised using 31P{1H}-NMR spectroscopy. 2 was reacted with selenourea resulting in the detection by ESIMS of the mixed- bridged …