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Showing 1 to 2 of 2 for “"Multivalent activation"”.
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Multivalent activation in temporary phosphate tethers: A new tether for small molecule synthesis
… esters as temporary tethers, capable of multivalent activation is the broad focus of the dissertation research reported herein. Specifically, the utility of phosphate tethers has been demonstrated through the divalent activation of allylic C2-symmetric monocyclic phosphates. Within these …
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Phosphate Tether-Mediated, One-Pot Metathesis Processes: Application in Small Molecule Synthesis
… (ii) possessing leaving group ability, (iii) multivalent activation of carbinol centers, (iv) protecting group attributes, and serving as a (v) temporary tether that can be removed under various conditions. Taken collectively, the reported bicyclo[4.3.1]phosphate (both enantiomers) undergoes …