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Showing 1 to 3 of 3 for “"Mukaiyama Reaction"”.
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The synthesis of derivatives of naturally occurring naphthalenes
… in an overall yield of 20%. The key step in this reaction sequence was the introduction of the C-6 methyl group via a regioselective lithiation/methylation reaction. Compounds which can be structurally defined as bioreductive alkylating agents have considerable potential as antineoplastic agents, …
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Quantenchemische Berechnungen zur enantioselektiv katalysierten Aldolreaktion
Die Mukaiyama-Aldolreaktion ist die Umsetzung eines Silylenolethers mit einer Carbonylverbindung in Gegenwart einer Lewis-Säure. Diese Reaktion ist eine wichtige Methode zur Knüpfung einer Kohlenstoff-Kohlenstoff-Bindung in der Organischen Chemie. In der vorliegenden Arbeit wird mittels …
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Synthese neuartiger Sulfoximine für die asymmetrische Metallkatalyse
… applicability in asymmetric phenyl transfer reactions onto aldehydes. Enantiomerically enriched diarylmethanols have been prepared by catalyzed asymmetric phenyl transfer reactions onto aromatic aldehydes with use of readily available beta-hydroxysulfoximines as catalysts. As the aryl source, …