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Showing 1 to 2 of 2 for “"Molybdenum dithiolene complexes"”.
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Building a Better Model for the Molybdenum Cofactor: A New Class of Molybdenum Dithiolene Complexes
<p>The molybdenum cofactor (Moco) is comprised of a molybdenum or tungsten center,at least one dithiolene chelate, and a tricyclic pyranopterin ligand. It is present in all living things, and it participates in global carbon, nitrogen, and sulfur cycles. The exact role the ligand plays in enzymatic …
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Understanding the Role of Ligand Oxidation State: Design, Synthesis, and Reactivity of Electronically Asymmetric Molybdenum Dithiolene Complexes
… posses a molybdopterin cofactor made up of a molybdenum metal center coordinated directly by a dithiolene ligand, which is appended to a pyranopterin cofactor. The majority of these enzymes catalyze oxygen atom transfer reactions that are concomitant with a transfer of two-electrons. We are …