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Showing 1 to 3 of 3 for “"Molybdenum compounds"”.
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Designing Volatile Molybdenum Compounds for Vapour-Phase Deposition
The vapor phase deposition of many molybdenum-containing films relies on the delivery of volatile compounds with the general bis(tert-butylimido)molybdenum(VI) framework. Herein the preparation and thermal characterization of several adducts of (tBuN)2MoCl2 with various neutral ligands is …
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Synthetic and mechanistic study of catalytic dintrogen reduction
… of a series of new triamidoamine based molybdenum compounds has been studied. The synthesis of a number of different triamidoamine ligands, and their resulting molybdenum compounds, is described. While symmetric variants containing electron-withdrawing hexaisopropyl terphenyl …
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Chemistry of highly reactive group 5 and 6 transition metal compounds
Trimethylphosphine complexes of tungsten and molybdenum have been used to model the coordination chemistry and reactivity that may be observed on the surface of an industrial hydrotreating catalyst. Most notably, it was observed that W(PMe₃)₄(η²-CH₂PMe₂))H is capable of (i) the unprecedented …