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Showing 1 to 5 of 5 for “"Molecule-Based Magnets"”.
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Molecule-Based Magnets Constructed From Hexacyanometalates
Improved preparations are given for several first-row transition metal trifluoromethanesulfonate (OTf) and p-toluenesulfonate (OTs) salts: M(OTf)x, where M = VII, VIII, CrII, MnII, CoII, NiII , and Cs, and [M(OH2)n][OTs]x, where M = TiIII, VIII, VIVO, Cr II, CrIII, MnII, FeII, CoII, NiII, and Cs. …
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Synthesis of New Molecule-Based Magnets using Bridging Organic Radicals
… that are candidates as building blocks of molecule-based ferrimagnets were synthesized and characterized. These families include fluorodicyanostilbenes, a tetrachlorodicyanostilbene, naphthyltricyanoethylenes, bromophenyltricyanoethylenes, and an anthryltricyanoethylene. The magnetic …
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Synthesis and Characterization of Molecule-Based Magnets Containing Methyl-Substituted Phenyltricyanoethylene Acceptors
A new family of molecule-based magnets related to the V[PTCE]x · yCH2Cl2 magnet (PTCE = phenyltricyanoethylene, x = ~2, y = ~0.2) was synthesized utilizing new reversible one-electron acceptors with the general form MexPTCE (PTCE = phenyltricyanoethylene, x is the number of methyl groups on the …
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The Synthesis and Coordination Chemistry of Two Families of Polydentate Ligands - Exploring Their Potential for the Preparation of Molecule-Based Magnets
… of (IV) at 200 K contains two independent molecules in the unit cell, both of which contain a hepta-coordinated Fe(II) and axial NCS ligands. Variable temperature magnetic susceptibility and structural studies are consistent with a high spin Fe(II) complex and show no evidence of any spin …
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In search for 3d/4f- and 4f-metal complexes with interesting magnetic and/or optical properties
… involvement in many fields/areas, e.g. single-molecule and single-ion magnetism, magnetic refrigeration, quantum computing, catalysis (both homogeneous and heterogeneous), optics, metal ion-assisted reactivity of organic compounds, and in the chemistry of multifunctional (or "hybrid") molecular …