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Showing 1 to 12 of 12 for “"Mof-5"”.
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The reactivity and cation exchange of MOF-5
… demonstrate that the inorganic clusters within MOF-5 can be derivatized with redox-active cations for subsequent use in coordination chemistry and small-molecule activation. Rather than reproduce known metal species, this work harnesses the intrinsic properties of the MOF-5 lattice to isolate …
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Hydrogen physisorptive storage in metal-organic frameworks (MOFs)
… of hydrogen using metal-organic frameworks (MOFs). MOFs are a class of porous inorganic-organic crystalline materials that store hydrogen by adsorption. What makes MOFs such an attractive option for hydrogen storage is that they have exceptionally high surface areas and porosity, as well as …
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Continuous production of two archetypal metal-organic frameworks using conventional and microwave heating
… last decade, with the number of publications and MOF structures registered with the Cambridge Crystallography database increasing year on year. One of the key reasons for this interest is the potential for very large internal surface areas of MOFs and the ability to tune pore sizes in order to …
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Oxygen atom transfer with manganese-exchanged metal-organic frameworks
… applied perspective. Metal-organic frameworks (MOFs) are an attractive platform for catalysis because they enable access to unique coordination environments and reactivities; this is due in part to their tunability combined with the site isolation offered by their solid state. In one example, …
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Cathodic electrodeposition of metal-organic frameworks
Metal-organic frameworks (MOFs) represent a class of functional coordination polymers with long-range order, great synthetic flexibility, and exceptionally high internal surface area. Although they have been proposed for a myriad of potential applications, many of these require that MOFs be …
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Hydrogen sorption in palladium doped microporous materials
… carbon), Black Pearls (carbon furnace black) and MOF-5 (metal organic framework) were all very low (<0.16 wt.%) at room temperature and 16 bar. Bridging the Black Pearls and Maxsorb carbon samples with 5 wt.% Pd/C resulted in fractionally higher hydrogen uptakes (0.01 wt.%). These results bore a …
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Katalysatordesign als Beitrag zu einer nachhaltigeren Chemie
… Ansatz auf mikro- bis mesoporöse Feststoffe (MOF-5, Silica) und funktionalisiert diese mit Palladiumnanopartikeln, so erhält man Speicherkapazitäten von bis zu 6 wt% an Wasserstoff.
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Functionalization of metal-organic frameworks with early transition metals : from fundamental studies to catalytic applications
Metal-organic frameworks (MOFs) have established themselves as some of the most versatile materials available, with applications ranging from gas sorption to separation to sensing to catalysis. With a large abundance of structural motifs published to date, research efforts have shifted towards …
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Controlling the Properties of Polymer Metal-Organic Frameworks and Cages Through Polymer Ligand Design
… Cages Strategies for developing polymer-tethered MOF/MOC hybrid materials are discussed. Emphasis is place on the impacts of synthetic strategy and polymer ligand design on the properties and applications of the end material. Chapter 2: PolyMOF Nanoparticles: Dual Roles of a Multivalent polyMOF …
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Cellulose-metal organic framework nanocomposite adsorbent films for water remediation
… synthesized metal-organic framework (MOF)/crystalline nanocellulose (CNC) composites, supported on a cellulose acetate (CA) substrate. Three adsorbent films were fabricated, i.e. CA-supported MOF-5/CNC (1), CA-supported Cu-BDC/CNC (2), and CA-supported Ni-BDC/CNC (3). This composition …
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Ionic Liquids for High Performance Solid-state Lithium Metal Batteries
… was injected into metal-organic framework (MOF-5) nanomaterials to improve the poly(ethylene oxide) (PEO) solid electrolyte and enhance the performance of solid- state lithium batteries. The results show that the formed nano-wetted interface structure can greatly improve the interface …