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Showing 1 to 2 of 2 for “"Mixed valent complexes"”.
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Cyanide-bridged polynuclear complexes
The three mixed valent dinuclear cyanide-bridged complexes LMCNFeCl3, (LM = Cp(dppe)Fe, Cp(dppe)Ru and Cp(PPh3)2Ru) were synthesized and characterized by X-ray single crystal determination, IR, UV-Vis and cyclic voltammograms, respectively. The three mixed valent dinuclear complexes display metal- …
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Ligand field considerations for the reactivity of high valent metal-oxo complexes and of bimetallic HX splitting photocatalysts
Inorganic molecular complexes are used to probe mechanistic steps in two reaction reactions related to energy storage. The first reaction considered is the O-O bond formation step required for water oxidation to oxygen. The second reaction considered is the photocatalytic generation of hydrogen and …