Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
Results
Showing 1 to 20 of 138 for “"Methyl-2"”.
-
The synthesis of methyl-2-acetamido-3,4,6-0-triacetyl alpha-D-talosaminide
… object of this project is to synthesize methyl N-acetyl α-D-talosaminide which has previously been prepared by Jeanloz (3) following a different route. The path that jeanloz, Jeanloz, and Glazer (3) followed involved the preparation of methyl 2-acetamide 4, 6-benzylidene 2-deoxy …
-
A study of the polymorphism of 4-methyl-2-nitroacetanilide and related compounds
… full crystal structures of three polymorphs of 4-methyl-2-nitroacetanilide (MNA) are described. The white form (MNA-l), is the most stable form. The least stable form is the amber farm (MNA-2). The yellow form (MNA-3) has been found to change in a topotactic manner into the white form. The …
-
Thermal decomposition of 2-methyl-2-propanesulfonyl chloride in the liquid and vapor phases
Electronic Thesis or Dissertation
-
Investigating the Cluster Chemistry of α-Methyl-2-pyridine methanol (mpmH) with Select 3d Ions
… potentially chiral bridging, chelating ligand, α-methyl-2-pyridinemethanol (mpmH) with select 3d ions for the discovery of polynuclear clusters with single molecule magnet (SMM) properties. Chapter 1 introduces the theory of molecular magnetism, SMMs and the concepts of chiral SMMs, magnetochiral …
-
Molecular dynamics simulation of penetrant transport in composite poly (4-methyl-2-pentyne) and nanoparticles of different types
… the penetrant transport in the composite Poly (4-methyl-2-pentyne) (PMP) and silica nanoparticle is being explored with molecular dynamics (MD) simulations. The structure of the PMP and amorphous silica nanoparticle composite was modeled and with the structure the variation of the cavity size …
-
The proof of structure of 9-cyclohexylanthracene and the syntheses of 2',3' and 4'-methyl-2-(α-naphthylmethyl)-benzophenones and 2-(α-naphthylmethyl)-benzophenone
In 1947, while working on the aromatic cyclodehydration of ketones to their corresponding substituted anthracenes, Vingiello (1a) attempted to prepare 9-cyclohexylanthracene using this method. It was evident in the cyclization of o-benzylcyelohexyl-phenone (I) that the hydrol (II) postulated as an …
-
Beta'-Lithiation of Alpha, Beta-Unsaturated Amides
… secondary and tertiary amides is reported. N-Methyl-1-cyclohexenecarboxamide and N-methyl-1-cyclopentenecarboxamide are metalated at nitrogen and at the (beta)'-carbon with either sec-butyllithium/TMEDA at -78(DEGREES)C or n-butyllithium at 0(DEGREES)C. Further reaction with a variety of …
-
Preparação e caracterização de complexos multicomponentes contendo ciclodextrinas e benznidazol
… polymers, triethanolamine (TEA) and 1-methyl-2- pyrrolidone (NMP) in benznidazole apparent aqueous solubility, as well as the formation of inclusion complexes was also investigated. The interactions in solution were predicted and investigated using phase solubility diagram methodology, …
-
Fluorinated amino acid derivatives
… in the syntheses of carboxylic acids. Methyl-, ethyl-, tert-butyl-, and benzyl 4-fluoro-3-methyl-2-pentenoates were synthesized in high yields by the Horner-Emmons reaction. The reaction is stereoselective and gave E and Z form in 75:25 ratio as determined from proton and fluorine nmr …
-
Platinum Complexes With Tridentate Ligands as Models for Active Monofunctional Anticancer Drugs
… (Ltri = di-(2-picolyl)amine (N(H)dpa), N-(6-methyl-2-picolyl)-N-(2-picolyl)amine (N(H)6-Medpa), di-(6-methyl-2-picolyl)amine (N(H)6,6′-Me2dpa), N-(6-methyl-2-picolyl)-N-(2-picolyl)amine (N(H)6,6′-Me2dpa), N(Me)-di-(6-methyl-2-picolyl)amine (N(Me)6,6′-Me2dpa), N(propionoic …
-
Specificity of aldehyde oxidase towards N-heterocyclic cations. Oxidation of quinolinium and related cations by aldehyde oxidase in vitro; the isolation of two products formed simultaneously from a single substrate.
… used required synthesis. Incubation of N-methylquinolinium, N-methyl-7,8-benzoquinolinium and N-phenylquinolinium yielded the corresponding 2- and 4-quinolones simultaneously. The ratio of 2- to 4-quinolone formation was found to be species dependent; the proportion of 4-quinolone was …
-
Poly(2-alkyl-2-oxazoline) containing multiphase systems
… iodobutane as an initiator. A kinetic study of 2-methyl-2-oxazoline polymerization in CD₃CN also indicated slower initiation than propagation rates using both butyl mesylate and butyl iodide as initiators. Based on the knowledge of 2-alkyl-2-oxazoline homopolymerizations, poly(2-alkyl-2-oxazoline) …
-
Synthesis of thromboxane A2 analogues.
… Three thromboxane A2 analogues were synthesized, methyl 7-[-5-(3-hydroxy-1-(E)-octenyl)-2-methylbicyclo[3.3.1]non-2-en-9-yl]-[syn]-(+/-)-5-(Z)-heptenoate, methyl 7-[-5-(hydroxy-1-(E)-octenyl)-2,2-dimethylbicyclo[3.3.1]non-9-yl]-[syn]-(-+)-5-(Z)-heptenoate and methyl …
-
Profiling and putative aroma biomarker identification for flavor in potatoes using a trained sensory panel and HS-SPME GC-MS
… 2-phenylacetaldehyde, the alcohol (Z)-2-methyl-2-penten-1-ol, and 5-methyl-2-hexanone, a ketone. Other positive flavor attributes, sweet and potato-like flavor, are related to benzoate-3-methyl-2-buten-1-ol, 2-ethylfuran, and 3,4,5-trimethyl-2-cyclopenten-1-one. Potential biomarkers for …
-
Biotransformation of aromatic hydrocarbons and organic sulphides by fungi
… arrhizus using the substrates 2-phenyl-, 2-methyl-2-phenyl-, and 2-phenyl-2-tert. butyl-l,3-oxathiolane. The relative stereochemistry of 2-methyl-2-phenyl-l,3-oxathiolan-l-oxide was assigned based on lH decoupling, n.O.e, 1 and H NMR experiments. The lH NMR (200 MHz) of the methylene protons …
-
Syntheses and Reactions of Novel Bicyclic Aryldialkoxybrominane and Aryldialkoxyiodinane Oxide
The synthesis of 4-methyl-2,6-bis{1-hydroxy-1-(trifluoromethyl)-2,2,2-trifluoroethyl}aniline (2) in several steps from 4-methyl-2-{1-hydroxy-1-(trifluoromethyl)-2,2,2-trifluoroethyl}aniline (5) provides a necessary precursor for the incorporation of a stabilizing tridentate ligand in compounds of …
-
The tandem chain extension -aldol reaction of beta-keto esters
… A control Reformatsky reaction with a methyl 2-iodo-5,5-dimethyl-4-oxo-hexanoate 53 and methyl 2-iodo-5,5-dimethylhexanoate 65 indicates that the presence of a gamma-keto-functionality in the zinc-organometallic intermediate in the TCEA reactions is key to the syn-selectivity that is …
Page 1 of 7