Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 8 of 8 for “"Metallopolymer"”.
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Self-Assembly of Functional Helical Metallopolymers
… This thesis proposes subcomponent self-assembled metallopolymers as a new and accessible class of material designed towards electronic and light-emitting applications. The metallopolymers are comprised of conjugated imine-based ligand strands that are helically wrapped around a linear array of …
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Synthesis, characterization, and lighting applications of group 11 metallopolymers with tunable phosphorescence
… and references is a study of group 11 monovalent metallopolymers. Three major chapters that involve synthetic strategies to obtain and enhance the phosphorescence of luminescent metallopolymer have been investigated. The first chapter includes an introduction to photoluminescence, luminescent …
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Synthesis and characterization of various ruthenium small molecules and metallopolymers for potential use in photovoltaic devices and luminescence properties of N-heterocyclic carbenes and trifluoro methylated tris(pyrazolyl)borate silver (I) acid-base adducts
… discusses the development of ruthenium-based metallopolymer and small molecular complexes toward possible utilization as active materials for solar cells. Such complexes have been found to be good "black absorbers" with solid-state absorption that spans the entire visible region into the …
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Synthesis of poly(NIPAM-co-vmbpy) microspheres and transition metal monomers for metallopolymeric material construction
… methylene-bis-acrylamide in order to attain metallopolymer microspheres with a high percentage of metal incorporation. Synthesis of 4-vinyl-4'-methyl-2,2'-bipyridine (vmbpy) was optimized from literature procedures for usage in the metal-containing monomers. Metal-containing monomers were …
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Redox-active materials for electrochemically-mediated separations
… Through principles of hydrophobicity, the metallopolymer can be engineered to activate in the presence of hydrophilic anions instead of hydrophobic ones, for subsequent application in the stable and 17-fold selective electrochemical extraction of perrhenate over nitrate. The ferrocene …
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[Ru-POM] Photo-electrocatalysis
… and the ruthenium polypyridyl complex or metallopolymers have been deposited onto electrodes using alternate immersion layer-by-layer assembly. Photocatalytic properties of the ruthenium polypyridyl:polyoxometalate adduct (Ru:POM) in electrolyte-free media was firstly studied. Although …
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Strained Metallocenophanes: Potential Monomers for Metallopolymers
In addition to the known sila[1]ferrocenophane Sp,Sp-119Me, four new planar-chiral sila[1]ferrocenophanes were prepared. Each new sila[1]ferrocenophanes was equipped with a benzyl group in the α-position, either on one or both Cp rings, and substituted on the bridging silicon atom, either by methyl …