Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 6 of 6 for “"Metal-organic polyhedra"”.
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Assemblies of Metal-Organic Polyhedra: Synthesis, Properties and Characterization
Metal-Organic Polyhedra (MOP) are nanoscale capsule-like supramolecular architectures composed of metal ions and organic linkers. They have well defined cavities depending on the ligand shape and metal-vertex geometry. The thesis concerns MOP composed of 12 copper(II) dimers (Cu24) and 24 …
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Construction of Metal-Organic Cages with Bimetallic Motifs and Self-Assembly of a Molecular Knot
… their general approach to designing new, complex metal-organic structures. The first portion of the thesis focuses on the self-assembly of metal-organic polyhedra built around bimetallic complexes. The components were specifically chosen to increase the chances of serendipitous and unexpected …
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Digital Chemical Engineering Across Scales and Domains: Case studies in electrochemistry, automated labs, and reticular materials
… pipeline that extracts synthesis procedures for metal-organic polyhedra from the literature using large language models, formalises them using ontologies, and integrates them into a machine-readable dataset. This knowledge base supports a rule-based method for predicting synthesis routes for …
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Toward the Synthesis of Designed Metal-Organic Materials
Metal-Organic Materials (MOMs) are an emerging class of crystalline solids that offer the potential for utilitarian design, as one of the greatest scientific challenges is to design functional materials with foreordained properties and eventually synthesize custom designed compounds for projected …
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Bismuth-, Tin-, and Lead-Containing Metal-Organic Materials: Synthesis, Structure, Photoluminescence, Second Harmonic Generation, and Ferroelectric Properties
<p>Metal-Organic Materials (MOMs) contain metal moieties and organic ligands that combine to form discrete (e.g. metal-organic polyhedra, spheres or nanoballs, metal-organic polygons) or polymeric structures with one-, two-, or three-dimensional periodicities that can exhibit a variety of …