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Showing 1 to 6 of 6 for “"Metal-Organic Cage"”.
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Surface chemistry of N-Heterocyclic carbenes and the self-assembly, structure, and properties of polymer metal-organic cage gels
… ligands for silicon and potentially other non-metallic substrates. Chapter 4. Cycloelimination of Imidazolidin-2-Ylidene N-Heterocyclic Carbenes: Mechanism and Insights into the Synthesis of Stable "NHC-CDI" Amidinates We report the discovery that 1,3-bis(aryl)imidazolidin-2-ylidenes, one of …
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Applications of Metal-Organic Cages: Synthesis of Atomically Precise Silver Clusters and Metal Extractant Materials
Metal–organic cages have demonstrated remarkable capabilities as functional materials in separations, sensing, and catalysis applications. However, the vast majority of cages are formed around mononuclear complexes at each vertex. This leaves the choice of organic components as the predominant …
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Sensors: Metal-Organic Cages and Graphene
… non-covalently functionalize the graphene using metal-organic cages. The metal-organic cages can encapsulate a small range of guests, however their binding inside the cage has not been investigated in the presence of graphene. Therefore, we present a novel investigation into the use of pristine …
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On the Structural Adaptability and Dynamics of Metal-Organic Cages
Metal-organic cages are molecular receptors that enable selective molecular recognition and catalysis, yet most current cage systems employ rigid building blocks that limit guest accommodation and environmental adaptability. Developing cages that combine structural integrity with conformational …
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Control of Network Topology in Photopolymer Networks for Additive Manufacturing
… We report a new class of supramolecular polymer metal-organic cage (polyMOC) gels based on the assembly of Cu24L24 cuboctahedra. We demonstrate how these polyMOCs can be reversibly photoswitched between three oxidation states (Cu(II), Cu(I), and Cu(0)) that each give rise to unique properties. …
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Stimuli-Induced Structural Transformations of Metal–Organic Cages
… and catalysis. Inspired by these systems, metal–organic cages (MOCs) have emerged as versatile synthetic platforms capable of undergoing controlled transformations in response to diverse stimuli. Studying the structural responsiveness of MOCs not only deepens our understanding of dynamic …