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Showing 1 to 5 of 5 for “"Metal Cluster Chemistry"”.
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Aspects of group 14 element - transition metal cluster chemistry
… Sn) have been reacted with various transition metal carbonyl anions. The Si[Co₂(CO)₇]₂/[Co(CO)₄]⁻ synthesis of [SiCo₉(CO)₂₁]²⁻, has also yielded [CCo₈(CO)₁₈]²⁻ (characterised by infrared spectroscopy and FABS mass spectroscopy) and [Cl₂SiCo₇(CO)₂₁]⁻ (characterised by X-ray crystallography as …
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Use of Oximes and Schiff-bases as Bridging/Chelating Ligands with Select 3d and 3d/4f Ions in Cluster Chemistry and a Mechanistic Insight into the Roles of Transition Metal Ions in the Formation of Tetrazoles
… N-naphthalidine-2-amino-naphthol (nanpH2) in homometallic 3d- and heterometallic 3d/4f-metal cluster chemistry has afforded a Mn cluster and novel families of Mn/Ln and Cu/Ln complexes. In Chapter 2, the synthesis and characterization of the {MnIIIMnIV2} (1), {GdMnIV2} (2) and {DyMnIV2} (3) …
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Polynuclear 3d/4f-Metal Complexes as Molecular Magnetic Refrigerants and Single-Molecule Magnets
… acenaphthenequinone dioxime (acndH2), in heterometallic 3d/4f-metal cluster chemistry has yielded two new families of polynuclear CuII/LnIII clusters. These complexes were found to exhibit interesting magnetic properties, specifically single-molecule magnetism and the magnetocaloric effect. In …
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High-Nuclearity Lanthanide(III) Complexes as Single-Molecule Magnets and Luminescent Materials
… acid (sacbH2), in lanthanide (LnIII) cluster chemistry has afforded four families of polynuclear and dinuclear complexes with new structural motifs, and interesting magnetic and optical properties. Chapter 1 deals with most of the fundamental aspects within the areas of polynuclear …
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Investigating the Cluster Chemistry of α-Methyl-2-pyridine methanol (mpmH) with Select 3d Ions
… describes an investigation of the coordination chemistry of the potentially chiral bridging, chelating ligand, α-methyl-2-pyridinemethanol (mpmH) with select 3d ions for the discovery of polynuclear clusters with single molecule magnet (SMM) properties. Chapter 1 introduces the theory of …