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Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 20 of 28 for “"Metal Carbides"”.
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Hydrogen Chemisorption and Oxidation on Transition Metal Carbides
Made available in DSpace on 2014-12-14T15:24:03Z (GMT). No. of bitstreams: 1 8004134.pdf: 3664469 bytes, checksum: 930bba133afa8c68baa82325bbb4f927 (MD5) Previous issue date: 1979
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Electron energy loss spectroscopy of transition-metal carbides
Submitted by Carolyn Mead (cmead2@illinois.edu) on 2011-06-13T14:57:08Z No. of bitstreams: 1 1983_allison.pdf: 3824629 bytes, checksum: c0a995c7c2bcca1cad4a44e6d628a004 (MD5)
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One pot synthesis of metal, carbides and polymeric aerogels
… dates to 3000 B.C. and is used to produce metal from the ore via chemical reduction with carbon. Carbon aerogels are produced by pyrolysis of purely organic resorcinol-formaldehyde (RF) aerogels. Here we have developed interpenetrating networks of RF and metal oxide (MOx) aerogels that upon …
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Carbon formation on metal carbides in chlorine-containing gases at high temperature.
Carbon formation on metal carbides in chlorine-containing gases at high temperature.
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Electronic structure and optical properties of layered ternary transition-metal carbides and nitrides
… (OLCAO) method. These layered ternary transition-metal carbides and nitrides are also commonly referred to as "MAX phases". Trends were observed for the calculated density of states (DOS) at Fermi-level, with respect to elemental variations and number of M and X layers. A local minimum of DOS(Ef) …
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NOVEL TYPES OF TWO-DIMENSIONAL METAL CARBIDES AND THEIR APPLICATIONS: FIRST PRINCIPLES STUDIES
Doping chemically active metal species into inert 2D carbon materials, such as graphene, graphyne, and graphdiyne, is widely adopted to design new functional structures. However, the doping-induced configurations generally suffer from poor stability, highly disordered lattices, and low metal …
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Synthesis, characterization and chemistry of two-dimensional transition metal carbides and nitrides (MXenes)
… family of two-dimensional (2D) early transition-metal carbides and nitrides first synthesized in 2011 from bulk layered crystalline MAX phases. Because of their 2D structure and unique combination of high conductivity and hydrophilicity, MXenes have raised a significant interest for various …
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Biofuels Production Via Catalytic Hydrocracking Of Ddgs Corn Oil And Hydrothermal Decarboxylation Of Oleic Acid Over Transition Metal Carbides Supported On Al-Sba-15
… grains with solubles (DDGS) corn oil over bimetallic carbide catalysts was explored for green diesel production. A catalyst composed of nickel−tungsten (Ni−W) carbide supported on Al-SBA-15 was designed based on the ability of nickel to adsorb and activate hydrogen and the potential of …
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Resistivity, Superconductivity, and Order-Disorder Transformations in Carbides and Carbohydrides
… to investigate electron transport in transition-metal carbides with special attention to ordering effects in substoichiometric carbides and to the influence of hydrogenation.
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Transition metal carbide and nitride nanoparticles with Noble metal shells as enhanced catalysts
… platform for enhancing the performance of noble metal catalysts while reducing the cost. Early transition metal carbides (TMCs) and nitrides (TMNs) have been identified as ideal core materials for supporting noble metal shells owing to their earth-abundance, thermal and chemical stability, …
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The influence of microstructure on the mechanical properties of some refractory compounds
… to the study of the microstructure of transition metal carbides and diborides. The local atomic structure of amorphous titanium diboride thin films, prepared by electron beam vaporization of the crystalline compound onto liquid nitrogen-cooled substrates, is examined using extended x-ray …
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Electrocatalysis In Li-S Batteries
… electrocatalysts such as WS2 nanosheets and Metal carbides for viable practical applications. Nature of electrocatalyst, concentration of polysulfides, temperature of the cell etc., on electrochemical properties will be discussed. We reveal substantial improvement in electrochemical …
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Sol-gel deposition of oxide-ion conducting thin films ; and, Liquid precursors to hafnium and tantalum carbides
… and the acetate or alkoxide of the dopant metal (Me). Copper-doped films were spincoated onto nonporous quartz substrates and pyrolyzed. These were initally defect-free, but became agglomerated on heating at higher temperatures. The use of a number of different additive compounds was tried, …
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MULTIFUNCTIONAL BEHAVIORS OF TWO-DIMENSIONAL MATERIALS AND THEIR COMPOSITES
… (2D) materials, including graphene, transition metal carbides or nitrides (TMC/Ns), have rich surface chemistry, superb electrical and mechanical properties. These unique properties make them ideal for multifunctional devices. Among them, we focused on graphene and TMC/Ns (i.e., MXenes), as well …
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Structural Characterization and Material Property Evaluation in Polymer-Derived SiOC Ceramics and Ceramic Nanocomposites
… growing class of two-dimensional transition metal carbides/nitrides) to create nanostructured ceramic composites. Phase formation, porosity, and electrical conductivity will be analyzed to demonstrate attractive multifunctional capabilities of SiOC ceramics. In addition, thermodynamic …
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Catalytic coatings for vanadium-based hydrogen membranes
… permeable alternative to palladium as a dense metallic hydrogen membrane. However, catalytic surface coatings must be applied to vanadium surfaces to enable the transport of molecular hydrogen. These coatings facilitate dissociation and recombination kinetics of molecular hydrogen and protect …
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Inkjet Printing of 2d Materials on Flexible and Rigid Substrates
… (2d) materials such as graphene, transition metal carbides, nitrides, or carbonitrides (MXenes) and hexagonal boron nitride (h-BN) hold enormous potential for the next generation printable electronics. When these materials are formulated into inkjet printable inks, they can be incorporated …
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THE STUDY AND CHARACTERIZATION OF A NEW PROCEDURE FOR APPLYING CARBIDE COATINGS TO GRAPHITE FURNACES USED IN ATOMIC ABSORPTION SPECTROSCOPY
… furnaces, under reduced pressure, with a liquid metal chloride. After soaking in water to hydrolyze the metal chloride to metal oxide, the furnace is fired at high temperature to form the carbide. Three metal chlorides, TiCl(,4), MoCl(,5) and WCl(,6), were used to apply TiC, MoC and WC coatings, …
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The impact of coating architecture on the hardness, friction and wear resistance of hard and tribological nanocomposite coatings
… coatings presented in this thesis include carbides that form a solid solution (Ti-Hf-C) as well as carbides that form composite microstructures (WC-SiC, HfC-SiC). Hardness measurements on these films indicated the potential of transition metal carbide-silicon carbide composites to be …
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