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Showing 1 to 2 of 2 for “"Mercaptan oxidation"”.

  1. Rational design of hydrogen-free catalytic active sites

    … thiols to disulfides and the photocatalytic oxidation of (S')-citronellol. The extreme electronic deficiency imparted on the metal complexes supports a new strategy for broadening catalytic activity to include thiols with poor basicity, which under normal circumstances cannot be oxidized. …

    njit Repository record for Rational design of hydrogen-free catalytic active sites (opens in a new tab)

  2. Fluorinated Metallo Phthalocyanines for Chemical and Biological Catalysis

    <p>The rational design of robust oxidation catalysts based on organic molecules is hindered by the presence of labile C-H bonds. We have shown recently that replacing all C-H bonds by a combination of fluoro- and perfluoro-groups in a bioinspired Cytochrome P450 model based on a phthalocyanine, Pc, …

    shu-thes Repository record for Fluorinated Metallo Phthalocyanines for Chemical and Biological Catalysis (opens in a new tab)