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Showing 1 to 2 of 2 for “"Matrixisolation"”.
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Synthese von Galliumhydriden aus intramolekular koordinierten Gallanen : Matrixisolation aus ab-initio-Rechnungen
The intramolecularly basecoordinated compounds of the type Me2N(CH2)3GaX2 (X = Cl, Br, N3, Me) undergo gasphasethermolysis in the temperature range between 700 and 1100 °C. The resulting products are trapped in Argon at 15 K using the rare gas matrix-isolation technique. Identification of the …
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The Electronic and Vibrational Spectroscopy of Metal Phthalocyanines and Metal Phthalocyanine Chlorides Isolated in Low Temperature Solids
… optical properties of the phthalocyanines. The matrixisolation technique provides an excellent opportunity to perform a detailed spectroscopic study of these molecules. Isolation of a molecule in an inert gas solid such as the rare gases or N2 at cryogenic temperatures allows for the acquisition …