Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
Results
Showing 1 to 4 of 4 for “"Matrix isolation studies"”.
-
A synthetic and computational approach to the design of new photoactive organometallic materials.
… is followed by an outline of the techniques of matrix isolation and time-resolved infrared (TRIR) spectroscopy. The rapidly developing area of computational chemistry is then introduced. Specific emphasis is placed on the ab-intio and Density Functional Theory (DFT) levels of theory as well as …
-
ELECTRONIC MATRIX ISOLATION SPECTROSCOPIC STUDIES OF METAL ATOM PHOTOCHEMISTRY
… an ultraviolet-visible absorption and emission matrix isolation apparatus is described, (2) by employing this apparatus, molecular scale interactions of the 1:1 metal-water adduct are investigated utilizing electronic absorption spectroscopy, and (3) molecular orbital and electronic …
-
Synthetic and mechanistic aspects of the reactions of α-diazosulfoxides
… pathways involved. In agreement with previous studies carried out on these compounds, the key reaction pathway of α-diazosulfoxides was found to be hetero-Wolff rearrangement to give α-oxosulfine intermediates. However, a competing reaction pathway involving oxygen migration from sulfur to …