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Showing 1 to 1 of 1 for “"Ligand binding (Biochemistry) g"”.
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Investigation of ligand misdirection using the kinetic element effect and the kinetic enthalpy effect.
Metal complexes were synthesized with the atropisomeric dabp. X-ray crystal structures were solved for [Ru(bipy)2(dabp)]2+ and [(eta6-C6H6)Ru(dabp)(Cl)]+. Only one diastereomer was observed for [Ru(bipy)2(dabp)] 2+ in the 1H NMR spectrum. Exchange was observed and measured for the ruthenium and …