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Showing 1 to 6 of 6 for “"Ligand Field Theory"”.
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Density Functional Theory augmented Multiplet Ligand Field Theory Applied to X-ray Spectroscopy of 3d Transition Metals
… to refine our understanding of the world, with theory playing a supporting or interpretive role. The rarer occurrence comes from when theory is used to motivate new directions for scientific exploration. The difficulty of course comes from the need for a theory that can provide predictions for …
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Crystal field aspects of vibrational spectra
Crystal Field Theory (C.F.T.), and its congeners, Ligand Field Theory (L.F.T.) and Molecular Orbital Theory (M.O.T.), have been most successful in explaining many of the properties of transition metal complexes. This is particularly true of their electronic spectra, magnetochemistry and chemical …
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Synthesis and characterisation of ligand-bridged tungsten and chromium penta- and tetra-carbonyl complexes
Ligand bridged metal carbonyl complexes of the form [5(CO)MLM(CO)5], [4(CO)MLM(CO)4] and [4(CO)ML], where M is either tungsten or chromium and L is either trans-l,2-(bis-4-pyridyl)ethylene(TBE) or 3,6-di-2-pyridyl-l,2,4,5-tetrazine (DPT) have been synthesised. They were characterised using IR, …
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The chemistry of ceramic glazes
… the investigation of the vanadyl ion in a weak ligand field, the situation of those found in a glaze environment (Chapter Three). In glaze recipes containing silica, potash feldspar, china clay, MO(M= Ca, Sr, Sa, Ti and Zn) and NiO, the ligand field theory is used in the elucidation of the …
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Chiral phosphine synthesis by the application of directed metallation
… to give a new hybrid chiral ditertiary phosphine ligand, "SemiPHOS", containing both a chiral phospholane ring and an adjacent diphenylphosphino group. SemiPHOS has been obtained in optically pure forms by a stereoselective synthesis and, independently, by a resolution procedure on its …
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Transition metal and actinide complexes with unsymmetrical alkyl chelates
Submission published under a 24 month embargo labeled 'U of I Access', the embargo will last until 2026-08-01