Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 4 of 4 for “"Ligand Control"”.
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EGF receptor-mediated fibroblast signaling and motility : role of nanoscale spatial ligand organization
… intracellular signaling. While integrin ligands are necessarily bound within the extracellular matrix to permit force transduction by the cell, the canonical view of growth factors is of soluble molecules freely diffusible and internalizable by the cell. Recent evidence suggests that in …
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Mechanistic Investigations Into The Thermal C-C Bond Forming Cyclization Of Metal Pyridine-Enamide Complexes And The Synthesis And Reactivity Of Cationic And Neutral Iron(Iv) Alkylidene Complexes
… pyridine adduct resulted in intraligand CC coupling to form an indolamide ligand. Control experiments with the corresponding lithium pyridine-enamide afforded the same indolamide. In order to probe the mechanism of cyclization, deuterium labeling experiments for the lithium …
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Stereoselective Intramolecular Rhodium(I)-Catalyzed [(3+2+2)] Cycloaddition Reactions of Alkylidenecyclopropanes (ACPs) for the Concise Synthesis of Bridged Tricyclic Products
… a compelling alternative to conventional chiral ligand control. Chapter 4 concludes the achievements and outlines future directions for advancing synthesis, including diastereodivergent approaches enabled by counterion control as well as the broader potential of the ACDC strategy to facilitate …
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Development of the cross-coupling of alcohols with olefins via positional tuning of the counterion in transition metal catalysis
Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2026-05-01