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Showing 1 to 20 of 217 for “"Lewis acid"”.

  1. Lewis acid catalysis in organic synthesis

    "Gadolinium triflate (Gd(OTf)₃) was found to be a simple and efficient catalyst for the acetylation of alcohols and amines in both conventional organic solvents and as well as in room temperature ionic liquids (TRIL). Acetylation reactions using acetic anhydride as the reagent proceed in excellent …

    must-thes Repository record for Lewis acid catalysis in organic synthesis (opens in a new tab)

  2. Studies on Lewis Acid-Base Adducts

    Made available in DSpace on 2014-12-10T23:01:16Z (GMT). No. of bitstreams: 1 7212280.pdf: 2128123 bytes, checksum: ac28befff6af3744a04c1efac9d7532f (MD5) Previous issue date: 1971

    uiuc Repository record for Studies on Lewis Acid-Base Adducts (opens in a new tab)

  3. Gas Phase Lewis Acid-Base Interactions

    Made available in DSpace on 2014-12-09T17:35:07Z (GMT). No. of bitstreams: 1 6503665.pdf: 4735633 bytes, checksum: 52109a08d7e92e8f90ec7b5e4956af0d (MD5) Previous issue date: 1964

    uiuc Repository record for Gas Phase Lewis Acid-Base Interactions (opens in a new tab)

  4. Calorimetric Investigations of Lewis Acid-Base Interactions

    Made available in DSpace on 2014-12-10T23:01:56Z (GMT). No. of bitstreams: 1 7500316.pdf: 3856228 bytes, checksum: 8a099174383142d44c149312c85aecba (MD5) Previous issue date: 1974

    uiuc Repository record for Calorimetric Investigations of Lewis Acid-Base Interactions (opens in a new tab)

  5. The Lewis Acid Properties of Titanium-Tetrafluoride

    Made available in DSpace on 2014-12-05T19:37:13Z (GMT). No. of bitstreams: 1 6000156.pdf: 3320366 bytes, checksum: 789b42765e2f9190645b95d900ee555a (MD5) Previous issue date: 1959

    uiuc Repository record for The Lewis Acid Properties of Titanium-Tetrafluoride (opens in a new tab)

  6. Structure and Stability of Lewis Acid-Base Adducts

    Made available in DSpace on 2014-12-10T23:01:46Z (GMT). No. of bitstreams: 1 7412107.pdf: 3678385 bytes, checksum: 03c7077b9aba6d33acf0f4ffd31d4b13 (MD5) Previous issue date: 1973

    uiuc Repository record for Structure and Stability of Lewis Acid-Base Adducts (opens in a new tab)

  7. Carbon-Carbon Bonds Formed by Lewis Acid Catalysis or Photoactivation

    … from propargylic alcohols, organoboronates, and Lewis acids. Lewis acids can also be used to facilitate a mild Friedel-Crafts reaction between electron-rich aromatics and allylic or benzylic alcohols. Moreover, these methods can be applied to the synthesis of natural products. Finally, …

    houston Repository record for Carbon-Carbon Bonds Formed by Lewis Acid Catalysis or Photoactivation (opens in a new tab)

  8. Nuclear Quadrupole Resonance Spectroscopy of Pyridine Lewis Acid-Base Complexes

    Made available in DSpace on 2014-12-13T20:10:50Z (GMT). No. of bitstreams: 1 8009152.pdf: 4399371 bytes, checksum: 166830e1084ef1dc8d40469273ca119e (MD5) Previous issue date: 1979

    uiuc Repository record for Nuclear Quadrupole Resonance Spectroscopy of Pyridine Lewis Acid-Base Complexes (opens in a new tab)

  9. Cooperative activation of biomass-derived oxygenates with Lewis acid zeolites

    … of oxygenated molecules owing to the unique Lewis acid character of their tetrahedral metal sites. Through fluoride-mediated synthesis, hydrophobic Lewis acid zeolites can behave as water-tolerant catalysts, which has resulted in a recent surge of experimental and computational studies in the …

    mit Repository record for Cooperative activation of biomass-derived oxygenates with Lewis acid zeolites (opens in a new tab)

  10. Catalytic implications of confined solvent ensembles within Lewis acid zeolites

    Lewis acidic zeolites are microporous crystalline materials that offer promise as catalysts for the activation and conversion of biomass-derived precursors in the liquid-phase due to their unique water-tolerance and synthetic versatility. The active site environment in zeolite catalysts is …

    mit Repository record for Catalytic implications of confined solvent ensembles within Lewis acid zeolites (opens in a new tab)

  11. Lewis-acid behaviour of neutral and cationic fluoridotungsten(V) and (VI) complexes

    lethbridge

  12. Probing the Impact of Solvent on Lewis Acid Catalysis via Fluorescent Lewis Adducts

    … have been developed to measure the strength of a Lewis acid. However, a major challenge for these measurements lies in the complexity that arises from variables, such as solvent and other fundamental interactions, as well as perturbations of Lewis acids as their reaction environment changes. …

    york Repository record for Probing the Impact of Solvent on Lewis Acid Catalysis via Fluorescent Lewis Adducts (opens in a new tab)

  13. Thermodynamic and Spectroscopic Studies of Reactivity and Bonding in Transition Metal Lewis Acid-Base Systems

    Made available in DSpace on 2014-12-13T20:09:53Z (GMT). No. of bitstreams: 1 7624127.pdf: 5375608 bytes, checksum: 63bf60c28ac8ad23c1ea568d2c74ac14 (MD5) Previous issue date: 1976

    uiuc Repository record for Thermodynamic and Spectroscopic Studies of Reactivity and Bonding in Transition Metal Lewis Acid-Base Systems (opens in a new tab)

  14. Lewis-acid and fluoride-ion donor properties of SF₄ and solid-state NMR spectroscopy of Me₃SnF

    lethbridge

  15. Studies in Asymmetric Catalysis: Lewis Base catalyzed/Lewis Acid Mediated Aldol Reactions of Ketone- and Amide Derived Nucleophiles

    Additionally, the use of the silicon tetrachloride---chiral phosphoramide system has proven a competent catalyst for highly selective vinylogous aldol reactions between dienolates derived from a variety of alpha,beta-unsaturated carbonyl compounds to aldehydes. These reactions provided high levels …

    uiuc Repository record for Studies in Asymmetric Catalysis: Lewis Base catalyzed/Lewis Acid Mediated Aldol Reactions of Ketone- and Amide Derived Nucleophiles (opens in a new tab)

  16. Stress relief: Exercising Lewis acid catalysis for donor-acceptor cyclopropane ring-opening annulations, a basis for new reaction methodologies

    … other relevant scaffolds. Unique, efficient, Lewis acid-catalyzed intramolecular cyclization strategies for the construction of functionalized polycycles using Friedel-Crafts-type alkylation sequences are presented to expand the reaction repertoire of the molecular architect. Generally, …

    gatech Repository record for Stress relief: Exercising Lewis acid catalysis for donor-acceptor cyclopropane ring-opening annulations, a basis for new reaction methodologies (opens in a new tab)

  17. Utilising Boron containing Lewis Acid Functions as "Stores" for Hydride and Other functional groups and its impact on Catalytic Reactions

    Transition metal mediated reactions play a vital role in the catalysis of many chemical transformations. Whilst most of these transformations occur at the metal centre, with ligands acting as spectators, new systems incorporating the direct involvement of coordinated ligands within catalytic cycles …

    southwales Repository record for Utilising Boron containing Lewis Acid Functions as "Stores" for Hydride and Other functional groups and its impact on Catalytic Reactions (opens in a new tab)

  18. On the Stereochemistry of Allylmetal-Aldehyde Condensations (Allyltrimethylsilane, Allyltributylstannane, Homoallylic Alcohols)

    … of double bonds was observed with the Lewis acid catalyzed reaction of 3a. The selectivity for 4 was dependent on Lewis acid. Cyclization induced by fluoride ion resulted in a stereochemical reversal. The Lewis acid and heat induced cyclization of 3b gave a large preference for the syn …

    uiuc Repository record for On the Stereochemistry of Allylmetal-Aldehyde Condensations (Allyltrimethylsilane, Allyltributylstannane, Homoallylic Alcohols) (opens in a new tab)

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