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Showing 1 to 20 of 217 for “"Lewis acid"”.
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Lewis acid catalysis in organic synthesis
"Gadolinium triflate (Gd(OTf)₃) was found to be a simple and efficient catalyst for the acetylation of alcohols and amines in both conventional organic solvents and as well as in room temperature ionic liquids (TRIL). Acetylation reactions using acetic anhydride as the reagent proceed in excellent …
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Studies on Lewis Acid-Base Adducts
Made available in DSpace on 2014-12-10T23:01:16Z (GMT). No. of bitstreams: 1 7212280.pdf: 2128123 bytes, checksum: ac28befff6af3744a04c1efac9d7532f (MD5) Previous issue date: 1971
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Gas Phase Lewis Acid-Base Interactions
Made available in DSpace on 2014-12-09T17:35:07Z (GMT). No. of bitstreams: 1 6503665.pdf: 4735633 bytes, checksum: 52109a08d7e92e8f90ec7b5e4956af0d (MD5) Previous issue date: 1964
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Calorimetric Investigations of Lewis Acid-Base Interactions
Made available in DSpace on 2014-12-10T23:01:56Z (GMT). No. of bitstreams: 1 7500316.pdf: 3856228 bytes, checksum: 8a099174383142d44c149312c85aecba (MD5) Previous issue date: 1974
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The Lewis Acid Properties of Titanium-Tetrafluoride
Made available in DSpace on 2014-12-05T19:37:13Z (GMT). No. of bitstreams: 1 6000156.pdf: 3320366 bytes, checksum: 789b42765e2f9190645b95d900ee555a (MD5) Previous issue date: 1959
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Structure and Stability of Lewis Acid-Base Adducts
Made available in DSpace on 2014-12-10T23:01:46Z (GMT). No. of bitstreams: 1 7412107.pdf: 3678385 bytes, checksum: 03c7077b9aba6d33acf0f4ffd31d4b13 (MD5) Previous issue date: 1973
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Carbon-Carbon Bonds Formed by Lewis Acid Catalysis or Photoactivation
… from propargylic alcohols, organoboronates, and Lewis acids. Lewis acids can also be used to facilitate a mild Friedel-Crafts reaction between electron-rich aromatics and allylic or benzylic alcohols. Moreover, these methods can be applied to the synthesis of natural products. Finally, …
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Nuclear Quadrupole Resonance Spectroscopy of Pyridine Lewis Acid-Base Complexes
Made available in DSpace on 2014-12-13T20:10:50Z (GMT). No. of bitstreams: 1 8009152.pdf: 4399371 bytes, checksum: 166830e1084ef1dc8d40469273ca119e (MD5) Previous issue date: 1979
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Cooperative activation of biomass-derived oxygenates with Lewis acid zeolites
… of oxygenated molecules owing to the unique Lewis acid character of their tetrahedral metal sites. Through fluoride-mediated synthesis, hydrophobic Lewis acid zeolites can behave as water-tolerant catalysts, which has resulted in a recent surge of experimental and computational studies in the …
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Catalytic implications of confined solvent ensembles within Lewis acid zeolites
Lewis acidic zeolites are microporous crystalline materials that offer promise as catalysts for the activation and conversion of biomass-derived precursors in the liquid-phase due to their unique water-tolerance and synthetic versatility. The active site environment in zeolite catalysts is …
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Probing the Impact of Solvent on Lewis Acid Catalysis via Fluorescent Lewis Adducts
… have been developed to measure the strength of a Lewis acid. However, a major challenge for these measurements lies in the complexity that arises from variables, such as solvent and other fundamental interactions, as well as perturbations of Lewis acids as their reaction environment changes. …
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Thermodynamic and Spectroscopic Studies of Reactivity and Bonding in Transition Metal Lewis Acid-Base Systems
Made available in DSpace on 2014-12-13T20:09:53Z (GMT). No. of bitstreams: 1 7624127.pdf: 5375608 bytes, checksum: 63bf60c28ac8ad23c1ea568d2c74ac14 (MD5) Previous issue date: 1976
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Studies in Asymmetric Catalysis: Lewis Base catalyzed/Lewis Acid Mediated Aldol Reactions of Ketone- and Amide Derived Nucleophiles
Additionally, the use of the silicon tetrachloride---chiral phosphoramide system has proven a competent catalyst for highly selective vinylogous aldol reactions between dienolates derived from a variety of alpha,beta-unsaturated carbonyl compounds to aldehydes. These reactions provided high levels …
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Stress relief: Exercising Lewis acid catalysis for donor-acceptor cyclopropane ring-opening annulations, a basis for new reaction methodologies
… other relevant scaffolds. Unique, efficient, Lewis acid-catalyzed intramolecular cyclization strategies for the construction of functionalized polycycles using Friedel-Crafts-type alkylation sequences are presented to expand the reaction repertoire of the molecular architect. Generally, …
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Utilising Boron containing Lewis Acid Functions as "Stores" for Hydride and Other functional groups and its impact on Catalytic Reactions
Transition metal mediated reactions play a vital role in the catalysis of many chemical transformations. Whilst most of these transformations occur at the metal centre, with ligands acting as spectators, new systems incorporating the direct involvement of coordinated ligands within catalytic cycles …
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On the Stereochemistry of Allylmetal-Aldehyde Condensations (Allyltrimethylsilane, Allyltributylstannane, Homoallylic Alcohols)
… of double bonds was observed with the Lewis acid catalyzed reaction of 3a. The selectivity for 4 was dependent on Lewis acid. Cyclization induced by fluoride ion resulted in a stereochemical reversal. The Lewis acid and heat induced cyclization of 3b gave a large preference for the syn …
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