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Showing 1 to 3 of 3 for “"Lanthanide chemistry"”.
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Deprotonated aza-crown ligands as simple and effective alternatives to C₅Me₅ in group 3, 4, and lanthanide chemistry
… aza-crown ether to allow isolation of soluble lanthanide and yttrium complexes has been investigated. A convenient route to these complexes has been demonstrated by the protonolysis reactions of Ln[(N(SiMe₃)₂]₃ with 4,13-diaza-18-crown-6. NMR spectroscopy and X-ray crystallography revealed a …
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Investigating and Enhancing Spin Reversal Barriers in Dinuclear 4f Single-Molecule Magnets and the Ultimate Shift to Mononuclear 3d Complexes
… been explored in this thesis using dinuclear lanthanide as well as mononuclear 3d complexes. In the pursuit of high-barrier SMMs via alignment of anisotropy axes, two dinuclear, quadruple-stranded helicates and one mesocate were isolated and are described in detail herein, both structurally …
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Functional Molecular Spacers for Plasmonic Nanojunctions: Design, Synthesis and Self-Assembly
… The second spacer class uses supramolecular chemistry to provide control over orientation, intermolecular coupling and Au affinity of aryl viologen (ArV) molecules within plasmonic nanocavities, using a macrocyclic cucurbit[n]uril (CB[n]) host. Successful self-assembly of AuNPs using various …