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Showing 1 to 1 of 1 for “"Kinetic isotope effects (KIE)"”.
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Proton-coupled electron transfer reactions in bio-inspired catalysis
… those based on hydrogenases. To understand the kinetics of this reaction, a nonadiabatic PCET rate theory is applied to predict and interpret kinetic isotope effects for Tyr-His model systems. Importantly, theory predicted new mediators capable of two proton transfers coupled to an electron …