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Showing 1 to 2 of 2 for “"Ketyl anion"”.
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Radical anion rearrangements. aryl cyclopropyl ketyl anions
… can be ascribed to the intermediacy of a ketyl anion. Through a detailed examination of the decay of electrolytically generated aryl cyclopropyl] ketyl anions, we have shown that the assumptions made in the use of these substrates as SET probes are not necessarily valid. Using derivative …
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Evaluation of 1,1-Dimethyl-5,7-Di-T-Butylspiro[2.5]Octa-4,7-Dien-6-One as a Mechanistic Probe for Single Electron Transfer
Single electron transfer (SET) mechanisms are becoming ubiquitous in modern organic chemistry. However, it is often difficult to distinguish SET mechanisms from polar mechanisms. Kinetics, products and product distributions, and response to perturbation in solvent and substituents are often …