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Showing 1 to 11 of 11 for “"Ionic self assembly"”.
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Liquid crystallinity and alignment of ionic self-assembly complexes
… type of liquid crystals is presented. This is ionic self-assembly (ISA) liquid crystals formed by introduction of oppositely charged ions between different low molecular tectonic units. As practically all conventional liquid crystals consist of rigid core and alkyl chains the attention is …
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Ionic self-assembly of porphyrin micro-nano structures for solar hydrogen evolution
This research project develops self-assembled porphyrin micro-nano structures and their metal nanocomposites for efficient solar H2 evolution. The project is composed of three inter-related tasks. The first task is to develop the synthetic methods for preparing the binary porphyrin micro-nano …
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Examining the Effects of Applied Potential on the Surface Charge of Functionalized Monolayers for Site-Directed Ionic Self Assembly
… the degree of potential-driven polyelectrolyte self assembly. The electrostatic interactions between the redox probe in solution and the terminal region of monolayers directly affects the extent of charge-transfer between the electrode and the redox probe in solution. For this reason, impedance …
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Novel surfactants for the production of functional nanostructured materials via the ionic self-assembly (ISA) route = Neuartige Tenside für die Synthese funktioneller nanostrukturierter Materialien durch ionische Selbsorganisation
… The present work describes the use of the ionic self-assembly (ISA) route to generate nanostructured materials with integrated functionality. Since the ISA strategy has proved to be a facile method for the production of liquid-crystalline materials, we investigated the phase behaviour, …
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Nonlinear Optical Properties and Structural Characteristics of Ionically Self-Assembled Nanoscale Polymer Films Influenced by Ionic Concentration and Incorporation of Monomer Chromophores
Ionically self-assembled monolayer (ISAM) films are typically an assemblage of oppositely charged polymers built layer by layer through coulombic attraction utilizing an environmentally friendly process to form ordered structures that are uniform, molecularly smooth, and physically robust. ISAM …
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Smart Polymer Electromechanical Actuators for Soft Microrobotic Applications
Ionic electroactive polymer (IEAP) actuators are a class of electroactive polymer devices that exhibit electromechanical coupling through ion transport in the device. They consist of an ionomeric membrane coated with conductive network composites (CNCs) and conductive electrodes on both sides. A …
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Second-Order Nonlinear Optical Responses in Tapered Optical Fibers with Self-Assembled Organic Multilayers
… fabricated by a novel hybrid covalent/ionic self-assembly multilayer technique. Despite the overall rotational symmetry of the nonlinear fiber, we observe significant second harmonic generation with ~ 400–500 fold enhancement of the SHG power compared to the traditional tapers. Phase …
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Modified Electrodes for Amperometric Determination of Glucose and Glutamate Using Mediated Electron Transport
… be able to detect glutamate in solution using ionic self-assembly methods. This was accomplished by preparing an ionically-self-assembled monolayer that included an electron transport mediator and an enzyme that would generate a current proportional to the concentration of analytes in solution. …
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Improvement of the Optical and Mechanical Properties of Silica Nanoparticle Ionic Self-Assembled Multilayer Anti-Reflection Coatings on Glass and Polycarbonate Substrates
… of silica nanoparticle films fabricated by ionic self-assembly, also known as layer-by-layer (LbL) deposition. Utilizing electrostatic attraction of oppositely-charged materials permits uniform and rapid growth of the constituents onto planar and curved surfaces. In this work, silica …
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Second-Order Nonlinear Optical Characteristics of Nanoscale Self-Assembled Multilayer Organic Films
Ionically self-assembled monolayer (ISAM) films are typically an assemblage of oppositely charged polymers built layer by layer through Coulombic attraction utilizing an environmentally friendly process to form ordered structures that are uniform, molecularly smooth and physically robust. ISAM …
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Self-organization on Nanoparticle Surfaces for Plasmonic and Nonlinear Optical Applications
… fabricated by nanosphere lithography with ionic self-assembled multilayer (ISAM) films, tuning the geometry of the particles to make their plasmonic resonances overlap with the frequency of optical excitation. The designed hybrid metallic/organic nanostructures exhibited large enhancements …